High electrocatalytic effect of Au-Pd alloy nanoparticles electrodeposited on microwave assisted sol-gel-derived carbon ceramic electrode for hydrogen evolution reaction

Various Au-Pd bimetallic nanoparticles were electrodeposited on microwave irradiated carbon ceramic electrodes (MWCCE). Au:Pd molar ratios of 75:25, 50:50 and 25:75 were electrodeposited on MWCCE and their electrocatalytic activities for hydrogen evolution reaction (HER) were evaluated. Among them, the alloy with Au:Pd molar ratio of 25:75 showed highest electrocatalytic activity for HER. The structure and nature of these alloys were characterized by scanning electron microscopy, X-ray diffraction, energy dispersive X-ray spectroscopy, inductively coupled plasma, and cyclic voltammetry. Alloying degree of bimetallic nanoparticles and electrodeposition time were optimized. The electrocatalytic activity of bimetallic nanoparticles was also compared with individual non-alloyed Au and Pd catalysts and the results showed that alloy nanoparticles have higher electrocatalytic activity for hydrogen evolution. The Tafel slopes ranges are obtained from 136 mV dec(-1) to 165 mV dec(-1) for HER on bare and modified MWCCE and kinetic parameters show that the Volmer step must control the HER. The stability of the best electrode is determined by chronopotentiometric and it showed a good stability. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.