One-dimensional self-assembly of a water soluble perylene diimide molecule by pH triggered hydrogelation

被引:120
作者
Datar, Aniket [1 ]
Balakrishnan, Kaushik [1 ,2 ]
Zang, Ling [1 ,3 ]
机构
[1] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA
[2] Univ Arizona, Coll Opt Sci, Tucson, AZ USA
[3] Univ Utah, Dept Mat Sci & Engn, Salt Lake City, UT 84112 USA
基金
美国国家科学基金会;
关键词
CHARGE-TRANSPORT; BISIMIDE DYES; SEMICONDUCTOR; NANOWIRES; GELATION;
D O I
10.1039/c3cc43359e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A water soluble perylene diimide molecule has been fabricated into nanofibers via a pH triggered hydrogelation route. The one-dimensional self-assembly is dominated by the intermolecular pi-pi stacking interactions in concert with the hydrogen bonding between the carboxylic acid side chains. The anisotropic electronic and optical properties observed for the nanofibers are consistent with the one-dimensional intermolecular pi-pi arrangement.
引用
收藏
页码:6894 / 6896
页数:3
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