Determination of the rate constants of the addition of primary alkyl radicals to allylstannanes

被引：0

作者：

Ferkous, F

Degueil-Castaing, M

Deleuze, H

Maillard, B ^{[1
]}

机构：

[1] Univ Bordeaux 1, Chim Organ & Organomet Lab, CNRS, UMR 5802, F-33405 Talence, France

[2] Univ Annaba, Inst Chim, Chim Organ Lab, Annaba, Algeria

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2002年 / 02期

关键词：

D O I：

10.1039/b108875k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rate constants and the activation parameters of the addition of primary alkyl radicals to allyldibutyl-4,7,10-trioxaundecylstannane 1 and (2-ethoxycarbonylprop-2-enyl)dibutyl-4,7,10-trioxaundecylstannane 2 were determined by studying their respective free radical reactions with (2-bromo-1,1-dimethylethyl)benzene and 6-bromohex-1-ene at different temperatures.

引用

页码：247 / 250

页数：4

共 19 条

[1] INTRAMOLECULAR META PHOTOCYCLOADDITION OF CONFORMATIONALLY RESTRAINED 5-PHENYLPENT-1-ENES .2. STERIC AND ELECTRONIC EFFECTS CAUSED BY 4-MONOSUBSTITUTION AND 4-DISUBSTITUTION
BARENTSEN, HM
SIEVAL, AB
CORNELISSE, J
[J]. TETRAHEDRON, 1995, 51 (27) : 7495 - 7520
[2] Intramolecular Addition In Hex-5-enyl, Hept-6-enyl, and Oct-7-enyl Radicals
Beckwith, Athelstan L. J.
Moad, Graeme
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1974, (12) : 472 - 473
[3] RATE CONSTANTS AND ARRHENIUS PARAMETERS FOR THE REACTIONS OF PRIMARY, SECONDARY, AND TERTIARY ALKYL RADICALS WITH TRI-NORMAL-BUTYLTIN HYDRIDE
CHATGILIALOGLU, C
INGOLD, KU
SCAIANO, JC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (26) : 7739 - 7742
[4] NUCLEOPHILIC CHARACTER OF ALKYL RADICALS .18. ABSOLUTE RATE CONSTANTS FOR THE ADDITION OF PRIMARY ALKYL RADICALS TO CONJUGATED OLEFINS AND 1,4-BENZOQUINONE
CITTERIO, A
ARNOLDI, A
MINISCI, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (15) : 2674 - 2682
[5] APPROXIMATE RATE CONSTANTS FOR THE ADDITION OF ALKYL RADICALS TO ALLYLSTANNANES
CURRAN, DP
VANELBURG, PA
GIESE, B
GILGES, S
[J]. TETRAHEDRON LETTERS, 1990, 31 (20) : 2861 - 2864
[6] An allylstannane reagent on non-cross-linked polystyrene support
Enholm, EJ
Gallagher, ME
Moran, KM
Lombardi, JS
Schulte, JP
[J]. ORGANIC LETTERS, 1999, 1 (05) : 689 - 691
[7] Free radical allyl transfers utilizing soluble non-cross-linked polystyrene and carbohydrate scaffold supports
Enholm, EJ
Gallagher, ME
Jiang, SJ
Batson, WA
[J]. ORGANIC LETTERS, 2000, 2 (21) : 3355 - 3357
[8] Ferkous F, 1997, MAIN GROUP MET CHEM, V20, P75
[9] FERKOUS F, 2001, CR HEBD ACAD SCI, P561
[10] Fischer H, 2001, ANGEW CHEM INT EDIT, V40, P1340, DOI 10.1002/1521-3773(20010417)40:8<1340::AID-ANIE1340>3.0.CO

← 1 2 →