A pentacycloundecane dimer

被引:2
作者
Kruger, HG [1 ]
Rademeyer, M [1 ]
Ramdhani, R [1 ]
机构
[1] Univ KwaZulu Natal, Sch Chem, ZA-4041 Durban, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词
D O I
10.1107/S160053680600403X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, 6,6-(3,6-diprop-2-enylpentacyclo-[6.2.1.0(2,7).0(4,10).0(5,9)]undecane-3,6-diyldioxy)pentacyclo[6.2.1.0(2,7).0(4,10).0(5,9)]undecan-3-one, C28H30O3, is a pentacyclo-undecane dimer. The molecule is chiral and contains two polycyclic pentacycloundecane cage units. Both enantiomers are present in the crystal structure. In the molecule, certain C - C bond lengths deviate from the normal value, with both short and long bonds present.
引用
收藏
页码:O966 / O968
页数:3
相关论文
共 12 条
[1]  
*BRUK, 1998, SAINT PLUS VERS 6 02
[2]  
*BRUK, 1998, SMART NT VERS 5 050
[3]   New software for searching the Cambridge Structural Database and visualizing crystal structures [J].
Bruno, IJ ;
Cole, JC ;
Edgington, PR ;
Kessler, M ;
Macrae, CF ;
McCabe, P ;
Pearson, J ;
Taylor, R .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397
[5]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[6]   5 8,11-SUBSTITUTED PENTACYCLO[5.4.0.02,6.03,10.05,9]UNDECANES [J].
FLIPPENANDERSON, JL ;
GEORGE, C ;
GILARDI, R ;
ZAJAC, WW ;
WALTERS, TR ;
MARCHAND, A ;
DAVE, PR ;
ARNEY, BE .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :813-817
[7]   Synthesis and transport studies of a new class of cage-annulated chiral macrocycles [J].
Govender, T ;
Hariprakasha, HK ;
Kruger, HG ;
Marchand, AP .
TETRAHEDRON-ASYMMETRY, 2003, 14 (11) :1553-1557
[8]   3,5-Bis(2-hydroxyethyl)-4-oxahexacyclo[5.4.1.02,6.03,10.05,9.08,11]dodecane [J].
Kruger, HG ;
Rademeyer, M ;
Ramdhani, R .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :O3968-O3970
[9]   Trifluoromethyl derivatives of pentacyclo[5.4.0.02,6.03,10.05,9]undecane [J].
Linden, A ;
Romanski, J ;
Mloston, G ;
Heimgartner, H .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 (04) :O221-O226
[10]   Synthesis, alkali metal picrate extraction, and alkali metal cation binding selectivities of some new cage-annulated polyoxamacrocyclic crown ethers [J].
Marchand, AP ;
Huang, ZL ;
Chen, ZB ;
Hariprakasha, HK ;
Namboothiri, INN ;
Brodbelt, JS ;
Reyzer, ML .
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2001, 38 (06) :1361-1368