Nonlinear polymeric effect:: synthesis, crystal structure and nonlinear optical properties of a new mercury iodide adduct polymer [Hg(bpfb)I2]n•2DMF (bpfb = N,N′-bis(4-pyridyl formamide)-1,4-benzene)

被引：35

作者：

Niu, YY

Song, YL

Wu, J

Hou, HW ^{[1
]}

Zhu, Y

Wang, X

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

[2] Harbin Inst Technol, Dept Appl Phys, Heilongjiang 150001, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

mercury (II) complex; crystal structure; nonlinear optical properties;

D O I：

10.1016/j.inoche.2004.01.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 1-D mercury iodide coordination polymer [Hg(bpfb)I-2](n).2DMF (1) (bpfb = N,N'-bis(4-pyridyl formamide)-1,4-benzene) was prepared. Its optical responses to the incident light exhibit strong three-order nonlinear optical absorptive and refractive effects with alpha(2) = 3.148 x 10(-16) m(2) W-1 and n(2) = 6.854 x 10(-18) m(2) W-1 in a 2.48 x 10(-4) mol dm(-3) DMF solution, and we find that a polymeric adduct may give better NLO properties than a monomeric adduct. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：471 / 474

页数：4

共 13 条

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CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (04) : 533 - 537
[2] Synthesis, structural characterization and optical refractive effect of coordination polymer [HgI2(bpea)]n(bpea=1, 2-bis(4-pyridyl)ethane)
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[3] Synthesis, structure and third-order nonlinear optical properties of a iodoargentate(I) cluster polymer of [(Et4N)(Ag2I3)]n
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[6] Hydrothermal Synthesis and Crystal Structure of a Cobalt(II) Coordination Polymer: [Co(C2O4)(bix)]n (bix = 1,4-Bis(imidazol-1-ylmethyl)-benzene)
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[7] Hydrothermal Synthesis and Crystal Structure of a Cobalt(II) Coordination Polymer: [Co(C2O4)(bix)]n (bix=1,4-Bis(imidazol-1-y1methyl)-benzene)
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[8] Halide-Directed Synthesis of Coordination Polymers [Hg2X4(ppt)]n (X=I and Br, ppt=1-(4-Pyridyl)-pyridinium-4-thiolate) with Different One-Dimensional Chain Structures and Third-Order Nonlinear Optical Properties
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[9] A helical chain coordination polymer {[Zn(Ac)2(bbbm)] (CH3OH)2}n (bbbm=1,1′-(1,4-butanediyl) bis-1H-benzimidazole):: synthesis, crystal structure and the third-order nonlinear optical property
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[10] Synthesis, crystal structure and magnetic properties of a 1D chain coordination polymer {[Cu(μ-H2L)(L)Cl](ClO4)3}∞ (L=N,N′-bis(pyridyl-3-yl-methyl)-1,5-diazacyclooctane)
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