Ultrasound assisted regioselective sulfonation of aromatic compounds with sulfuric acid

被引：10
|
作者：
Qureshi, Ziyauddin S. [1 ]
Deshmukh, Krishna M. [1 ]
Jagtap, Sachin R. [1 ]
Nandurkar, Nitin S. [1 ]
Bhanage, Bhalchandra M. [1 ]
机构：
[1] Univ Mumbai, Dept Chem, Inst Chem Technol, Bombay 400019, Maharashtra, India
来源：
ULTRASONICS SONOCHEMISTRY | 2009年 / 16卷 / 03期
关键词：
Ultrasound; Sulfonation; Aromatic hydrocarbon; Sulfuric acid; DILUTE NITRIC-ACID; PHENOLS; NITRATION; TRIOXIDE;
D O I：
10.1016/j.ultsonch.2008.10.001
中图分类号：
O42 [声学];
学科分类号：
070206 ; 082403 ;
摘要：
A simple and convenient methodology for selective sulfonation of aromatic compounds using sulfuric acid under sonication is described. The present methodology shows a considerable enhancement in the reaction rate along with improved selectivity compared with the reactions performed under silent conditions. The effect of various parameters such as agitation speed, sulfuric acid concentration, and temperature on reaction system have been investigated and are explained on the basis of ultrasonically generated cavitational effects. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：308 / 311
页数：4
相关论文
共 50 条
  • [41] REACTION OF IODOANISOLES WITH SULFURIC-ACID - REVERDIN REARRANGEMENT-LIKE REACTION IN AROMATIC SULFONATION
    MURAMOTO, Y
    ASAKURA, H
    SUZUKI, H
    NIPPON KAGAKU KAISHI, 1978, (02) : 259 - 264
  • [42] The sulfonation of aromatic and heteroaromatic polycyclic compounds
    Katritzky, Alan R.
    Kim, Myong Sang
    Fedoseyenko, Dmytro
    Widyan, Khalid
    Siskin, Mike
    Francisco, Manuel
    TETRAHEDRON, 2009, 65 (06) : 1111 - 1114
  • [43] Microwave assisted sulfonation of 2-naphthol by sulfuric acid: Cleaner production of Schaeffer's acid
    Urnrigar, Vaishali M.
    Chakraborty, Mousumi
    Parikh, Parimal A.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (19) : 6217 - 6220
  • [44] SULFONATION OF POLYETHERSULFONE IN CONCENTRATED SULFURIC-ACID
    SHIBUYA, N
    PORTER, RS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 221 - PMSE
  • [45] Kinetics of PEEK sulfonation in concentrated sulfuric acid
    Shibuya, N.
    Porter, R.S.
    Polymer Preprints, Division of Polymer Chemistry, American Chemical Society, 1992, 33 (01):
  • [46] SULFONATION OF PHENANTHRENE BY SULFURIC-ACID IN NITROBENZENE
    KACHURIN, OI
    VASILENK.VY
    FEDORCHU.ES
    VELICHKO, LI
    ZHURNAL ORGANICHESKOI KHIMII, 1973, 9 (09): : 1945 - 1947
  • [47] AROMATIC SULFONATION .104. SULFONATION AND SULFATION OF 1,3-DIHYDROXYBENZENE AND ITS METHYL ETHERS IN CONCENTRATED SULFURIC-ACID
    CERFONTAIN, H
    KOEBERGTELDER, A
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1988, 107 (09): : 543 - 548
  • [48] Iodination of aromatic compounds with iodine monochloride in aqueous sulfuric acid
    Chaikovskii, VK
    Filimonov, VD
    Kharlova, TS
    Chernova, TN
    Sharapova, ES
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2000, 36 (05) : 666 - 670
  • [49] ON THE ASSOCIATION OF CONDENSED POLYCYCLIC AROMATIC COMPOUNDS IN CONCENTRATED SULFURIC ACID
    HANDA, T
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1962, 35 (08) : 1361 - 1366
  • [50] AROMATIC SULFONATION .64. SULFONATION OF BIPHENYLMONOSULFONIC ACIDS AND SOME OTHER BIPHENYLS, CONTAINING A DEACTIVATING SUBSTITUENT, IN CONCENTRATED SULFURIC-ACID
    KORTEKAAS, TA
    CERFONTAIN, H
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1978, (05): : 445 - 449
12345