Ultrasound assisted regioselective sulfonation of aromatic compounds with sulfuric acid

被引:10
作者
Qureshi, Ziyauddin S. [1 ]
Deshmukh, Krishna M. [1 ]
Jagtap, Sachin R. [1 ]
Nandurkar, Nitin S. [1 ]
Bhanage, Bhalchandra M. [1 ]
机构
[1] Univ Mumbai, Dept Chem, Inst Chem Technol, Bombay 400019, Maharashtra, India
关键词
Ultrasound; Sulfonation; Aromatic hydrocarbon; Sulfuric acid; DILUTE NITRIC-ACID; PHENOLS; NITRATION; TRIOXIDE;
D O I
10.1016/j.ultsonch.2008.10.001
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
A simple and convenient methodology for selective sulfonation of aromatic compounds using sulfuric acid under sonication is described. The present methodology shows a considerable enhancement in the reaction rate along with improved selectivity compared with the reactions performed under silent conditions. The effect of various parameters such as agitation speed, sulfuric acid concentration, and temperature on reaction system have been investigated and are explained on the basis of ultrasonically generated cavitational effects. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:308 / 311
页数:4
相关论文
共 20 条
  • [1] ABDOL RH, 2004, TETRAHEDRON LETT, V45, P6607
  • [2] Low temperature recyclable catalyst for Heck reactions using ultrasound
    Ambulgekar, GV
    Bhanage, BM
    Samant, SD
    [J]. TETRAHEDRON LETTERS, 2005, 46 (14) : 2483 - 2485
  • [3] Ultrasound promoted selective synthesis of 1,1′-binaphthyls catalyzed by Fe impregnated pillared Montmorillonite K10 in presence of TBHP as an oxidant
    Bhor, Malhari D.
    Nandurkar, Nitin S.
    Bhanushali, Mayur J.
    Bhanage, Bhalchandra M.
    [J]. ULTRASONICS SONOCHEMISTRY, 2008, 15 (03) : 195 - 202
  • [4] Bochkareva T.P., 1989, J. Org. Chem. USSR, V25, P1346
  • [5] CERFONTAIN H, 1985, J CHEM SOC PERK T 2, P659, DOI 10.1039/p29850000659
  • [6] CORBY BW, 2002, CHEM RES SYNOP, V7, P326
  • [7] Phase-transfer catalysis and ultrasonic waves II: saponification of vegetable oil
    Entezari, MH
    Keshavarzi, A
    [J]. ULTRASONICS SONOCHEMISTRY, 2001, 8 (03) : 213 - 216
  • [8] Gilbert E.E., 1965, SULFONATION RELATED
  • [9] A novel method for sulfonation of aromatic rings with silica sulfuric acid
    Hajipour, AR
    Mirjalili, BBF
    Zarei, A
    Khazdooz, L
    Ruoho, AE
    [J]. TETRAHEDRON LETTERS, 2004, 45 (35) : 6607 - 6609
  • [10] Ultrasound-assisted synthesis of β-enaminonitriles in the presence of base
    Jagtap, Sachin R.
    Bhanushali, Mayur J.
    Nandurkar, Nitin S.
    Bhanage, Bhalchandra M.
    [J]. SYNTHETIC COMMUNICATIONS, 2007, 37 (13) : 2253 - 2258