Ultrasound assisted regioselective sulfonation of aromatic compounds with sulfuric acid

被引:10
|
作者
Qureshi, Ziyauddin S. [1 ]
Deshmukh, Krishna M. [1 ]
Jagtap, Sachin R. [1 ]
Nandurkar, Nitin S. [1 ]
Bhanage, Bhalchandra M. [1 ]
机构
[1] Univ Mumbai, Dept Chem, Inst Chem Technol, Bombay 400019, Maharashtra, India
关键词
Ultrasound; Sulfonation; Aromatic hydrocarbon; Sulfuric acid; DILUTE NITRIC-ACID; PHENOLS; NITRATION; TRIOXIDE;
D O I
10.1016/j.ultsonch.2008.10.001
中图分类号
O42 [声学];
学科分类号
070206 ; 082403 ;
摘要
A simple and convenient methodology for selective sulfonation of aromatic compounds using sulfuric acid under sonication is described. The present methodology shows a considerable enhancement in the reaction rate along with improved selectivity compared with the reactions performed under silent conditions. The effect of various parameters such as agitation speed, sulfuric acid concentration, and temperature on reaction system have been investigated and are explained on the basis of ultrasonically generated cavitational effects. (c) 2008 Elsevier B.V. All rights reserved.
引用
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页码:308 / 311
页数:4
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