KINETICS OF OXIDATION OF CROTYL ALCOHOL BY TETRAETHYLAMMONIUM CHLOROCHROMATE

被引：0
作者：
Awasthi, Anupam [1 ]
Singh, J. V. [1 ]
机构：
[1] Nehru Coll, Dept Chem, Kannauj 209721, UP, India
来源：
OXIDATION COMMUNICATIONS | 2013年 / 36卷 / 02期
关键词：
kinetics; oxidation; mechanism; crotyl alcohol; tetraethylammonium chlorochromate; QUINOLINIUM CHLOROCHROMATE; CHROMIUM(VI) COMPOUNDS; ACID; CROTONALDEHYDE; MECHANISM; QCC;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The kinetics of oxidation of crotyl alcohol by tetraethylammonium chlorochromate (TEACC) has been investigated in acetic acid-water mixtures (50% v/v) medium. The reaction exhibits first order kinetics, each in [TEACC] and [crotyl alcohol]. The reaction is catalysed by hydrogen ions and a medium of low dielectric constant favours the oxidation process. Ionic strength variation has no significant effect on the reaction rate. The reaction does not induce polymerisation of acrylonitrile. Activation and thermodynamic parameters have been computed and a suitable mechanism consistent with kinetic data has been proposed.
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页码：355 / 360
页数：6
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