Binary Janus Porous Coordination Polymer Coating for Sensor Devices with Tunable Analyte Affinity

被引:119
作者
Meilikhov, Mikhail [1 ]
Furukawa, Shuhei [1 ,2 ]
Hirai, Kenji [3 ]
Fischer, Roland A. [4 ]
Kitagawa, Susumu [1 ,2 ,3 ]
机构
[1] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCEMS, Sakyo Ku, Kyoto 6068501, Japan
[2] Japan Sci & Technol Agcy JST, ERATO Kitagawa Integrated Pores Project, Shimogyo Ku, Kyoto 6008815, Japan
[3] Kyoto Univ, Grad Sch Eng, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[4] Ruhr Univ Bochum, Dept Inorgan Chem 2, D-44780 Bochum, Germany
关键词
coordination polymers; heterostructures; interfaces; metal-organic frameworks; surface modification; METAL-ORGANIC FRAMEWORKS; PARTICLES; FUNCTIONALIZATION; NANOPARTICLES; MICELLES; CRYSTALS; HYDROGEN; STORAGE;
D O I
10.1002/anie.201207320
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Janus MOF: Thin films consisting of noncentrosymmetric heterostructured metal-organic frameworks (MOFs) were fabricated directly on quartz-crystal microbalance (QCM) sensor devices. Depending on the spatial configuration of two frameworks, the thin MOF films could tune the affinity for analytes, thus giving high selectivity to the QCM sensors. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:341 / 345
页数:5
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