Solvent-dependent moulding of porphyrin-based nanostructures: solid state, solution and on surface self-assembly

被引：11
作者：
Dordevic, Luka [1 ]
Demitri, Nicola [2 ]
Bonifazi, Davide [1 ,3 ]
机构：
[1] Univ Trieste, INSTM UdR Trieste, Dept Chem & Pharmaceut Sci, Trieste, Italy
[2] Elettra Sincrotrone Trieste, Trieste, Italy
[3] Cardiff Univ, Sch Chem, Cardiff, S Glam, Wales
来源：
SUPRAMOLECULAR CHEMISTRY | 2016年 / 28卷 / 9-10期
关键词：
Porphyrin; nanostructures; H-bonding; soft-matter; CHLOROSOMAL BACTERIOCHLOROPHYLL-C; ARTIFICIAL ANTENNA SYSTEMS; ZINC CHLORIN; SUPRAMOLECULAR ORGANIZATION; ENERGY-TRANSFER; COMPLEX MATTER; POLYMERS; AGGREGATE; BACTERIA; STACKS;
D O I：
10.1080/10610278.2016.1158407
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel porphyrin derivative 1.Zn was synthesised in order to mimic the self-assembly properties of natural light-harvesting antennas and its self-assembly behaviour in solution and in solid state were studied by NMR and X-Ray spectroscopies. The self-assembly of this molecule was triggered in apolar solvents and studied in solution by UV-Vis spectroscopy, suggesting it is able to form slipped face-to-face aggregates, or J-aggregates. The nanoscopic and microscopic morphology of the aggregates was elucidated by atomic force microscopy, revealing the formation of extended two-dimensional structures. [GRAPHICS] .
引用
收藏
页码：753 / 761
页数：9
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