First synthesis and electronic properties of (hetero)aryl bridged and directly linked redox active phenothiazinyl dyads and triads

被引：75
作者：
Krämer, CS [1 ]
Zeitler, K [1 ]
Müller, TJJ [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 49期
关键词：
D O I：
10.1016/S0040-4039(01)01848-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Phenothiazinyl dyads and triads with variable functionalization can be synthesized in good yields by Suzuki coupling with suitable phenothiazinyl boronates. In addition, the structure of the phenylated phenothiazine (6) has been corroborated by an X-ray structure analysis. According to cyclic voltammetry these oligofunctional heterocyclic oligomers are strongly electronically coupled and represent suitable functional units for novel redox active molecular wires. (C) 2001 Elsevier Science Ltd. All rights reserved.
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页码：8619 / 8624
页数：6
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