A green and facile approach for hydrothermal synthesis of LiFePO4 using iron metal directly

被引：37
|
作者：
Bolloju, Satish [1 ]
Rohan, Rupesh [1 ]
Wu, Shao-Tzu [1 ]
Yen, Ho-Xin [1 ]
Dwivedi, Gopeshwar D. [2 ]
Lin, Yuya A. [1 ]
Lee, Jyh-Tsung [1 ,3 ]
机构：
[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan
[2] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 80424, Taiwan
[3] Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 80708, Taiwan
来源：
ELECTROCHIMICA ACTA | 2016年 / 220卷
关键词：
hydrothermal synthesis; LiFePO4; iron metal; cathode; lithium-ion batteries; LITHIUM-ION BATTERIES; CARBOTHERMAL REDUCTION METHOD; X-RAY-DIFFRACTION; CATHODE MATERIALS; ELECTROCHEMICAL PROPERTIES; SUPERCRITICAL WATER; CARBON NANOTUBES; PHOSPHO-OLIVINES; COMPOSITE; DEPENDENCE;
D O I：
10.1016/j.electacta.2016.10.066
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Hydrothermal LiFePO4 has been successfully synthesized using iron powder as an iron source and as an in situ reducing agent. The 100% atom economy delivered by iron metal (Fe-0) makes this process green and inexpensive. A plausible mechanism for the formation of hydrothermal LiFePO4 powder is also proposed. The structure of the LiFePO4 powder is well characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy techniques. The discharge capacity of the LiFePO4 electrode is found to be 165 mAhg(-1) at 0.1 C-rate, and the cycle-life performance is comparable to the conventionally synthesized LiFePO4. (c) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：164 / 168
页数：5
相关论文
共 50 条
  • [11] Synthesis of LiFePO4/C as cathode material by a novel optimized hydrothermal method
    Ge Gao
    Aifang Liu
    Zhonghua Hu
    Yuanyuan Xu
    Yafei Liu
    Rare Metals, 2011, 30 : 433 - 438
  • [12] Synthesis of LiFePO4 /C as cathode material by a novel optimized hydrothermal method
    GAO Ge
    RareMetals, 2011, 30 (05) : 433 - 438
  • [13] Hydrothermal synthesis and properties of manganese-doped LiFePO4
    Zhao, Rui-Rui
    Lan, Bing-Yan
    Chen, Hong-Yu
    Ma, Guo-Zheng
    IONICS, 2012, 18 (09) : 873 - 879
  • [14] Hydrothermal Synthesis of Leaf-like LiFePO4/C Cathode Composites
    Yun Qiang
    Zhou Yuan
    Hai Chun-Xi
    Shen Yue
    Li Xiang
    Zhang Li-Juan
    Li Song
    Ding Xiu-Ping
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2015, 31 (05) : 880 - 887
  • [15] Synthesis of LiFePO4/C as cathode material by a novel optimized hydrothermal method
    Gao Ge
    Liu Aifang
    Hu Zhonghua
    Xu Yuanyuan
    Liu Yafei
    RARE METALS, 2011, 30 (05) : 433 - 438
  • [16] Enhanced performance of LiFePO4 through hydrothermal synthesis coupled with carbon coating and cupric ion doping
    Pei, Bo
    Wang, Qiang
    Zhang, Weixin
    Yang, Zeheng
    Chen, Min
    ELECTROCHIMICA ACTA, 2011, 56 (16) : 5667 - 5672
  • [17] Hierarchy concomitant in situ stable iron(II)-carbon source manipulation using ferrocenecarboxylic acid for hydrothermal synthesis of LiFePO4 as high-capacity battery cathode
    Yen, Hoxin
    Rohan, Rupesh
    Chiou, Chun-Yu
    Hsieh, Chang-Ju
    Bolloju, Satish
    Li, Chia-Chen
    Yang, Yi-Fei
    Ong, Chi-Wi
    Lee, Jyh-Tsung
    ELECTROCHIMICA ACTA, 2017, 253 : 227 - 238
  • [18] Solid state synthesis of LiFePO4/C: using low cost materials
    Islam, Mobinul
    Yoon, Man-Soon
    Park, Young Min
    Ur, Soon-Chul
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2015, 16 (02): : 218 - 222
  • [19] Synthesis and Electrochemical Performance of LiFePO4
    Zhang, Zi-lu
    Lu, Jia-chun
    PROCEEDINGS OF THE 7TH NATIONAL CONFERENCE ON CHINESE FUNCTIONAL MATERIALS AND APPLICATIONS (2010), VOLS 1-3, 2010, : 1667 - 1669
  • [20] Rapid Synthesis of LiFePO4 by Coprecipitation
    Huang, Chaochao
    Ai, Desheng
    Wang, Li
    He, Xiangming
    CHEMISTRY LETTERS, 2013, 42 (10) : 1191 - 1193
12345