Interacting hard rods on a lattice: Distribution of microstates and density functionals

被引:9
作者
Bakhti, Benaoumeur [1 ]
Mueller, Gerhard [2 ]
Maass, Philipp [1 ]
机构
[1] Univ Osnabruck, Fachbereich Phys, D-49076 Osnabruck, Germany
[2] Univ Rhode Isl, Dept Phys, Kingston, RI 02881 USA
关键词
PERCUS-YEVICK APPROXIMATION; PHASE-TRANSITIONS; PROTEIN SOLUTIONS; SPHERE FLUIDS; GAS PROBLEMS; MODEL; ADHESION; SYSTEMS; EQUILIBRIUM; SEPARATION;
D O I
10.1063/1.4816379
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We derive exact density functionals for systems of hard rods with first-neighbor interactions of arbitrary shape but limited range on a one-dimensional lattice. The size of all rods is the same integer unit of the lattice constant. The derivation, constructed from conditional probabilities in a Markov chain approach, yields the exact joint probability distribution for the positions of the rods as a functional of their density profile. For contact interaction ("sticky core model") between rods, we give a lattice fundamental measure form of the density functional and present explicit results for contact correlators, entropy, free energy, and chemical potential. Our treatment includes inhomogeneous couplings and external potentials. (C) 2013 AIP Publishing LLC.
引用
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页数:7
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