Synthesis of metal-organic frameworks: A mini review

被引：467

作者：

Lee, Yu-Ri ^{[1
]}

Kim, Jun ^{[1
]}

Ahn, Wha-Seung ^{[1
]}

机构：

[1] Inha Univ, Dept Chem & Chem Engn, Inchon 402751, South Korea

来源：

KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2013年 / 30卷 / 09期

基金：

新加坡国家研究基金会;

关键词：

Metal Organic Frameworks (MOFs); Zeolitic Imidazolate Frameworks (ZIFs); Solvothermal/Hydrothermal Synthesis; Microwave; Sonochemistry; Electrochemical Synthesis; Mechanochemical Synthesis; ROOM-TEMPERATURE SYNTHESIS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; CHROMIUM TEREPHTHALATE MIL-101; IONOTHERMAL SYNTHESIS; MICROWAVE SYNTHESIS; CARBON-DIOXIDE; SONOCHEMICAL SYNTHESIS; CATALYTIC-PROPERTIES; MOLECULAR-SIEVES; CO2; ADSORPTION;

D O I：

10.1007/s11814-013-0140-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal organic frameworks (MOFs) are porous crystalline materials of one-, two-, or three-dimensional networks constructed from metal ions/clusters and multidentate organic linkers via coordination bonding, which are emerging as an important group of materials for energy storage, CO2 adsorption, alkane/alkene separation, and catalysis. To introduce newcomers in chemical engineering discipline to the rapidly expanding MOF research works, this review presents a brief introduction to the currently available MOFs synthesis methods. Starting from the conventional solvothermal/hydrothermal synthesis, microwave-assisted, sonochemical, electrochemical, mechanochemical, ionothermal, drygel conversion, and microfluidic synthesis methods will be presented. Examples will be limited to those representative MOP structures that can be synthesized using common organic ligands of 1,4-benzenedicarboxylic acid (and its functionalized forms) and 1,3,5-benzenetricarboxylic acid, in conjunction with metal nodes of Zn2+, Cu2+, Cr3+, Al3+, Fe3+ and Zr4+ Synthesis of widely-investigated zeolitic imidazolate framework (ZIP) structure, LIF-8 is also included.

引用

页码：1667 / 1680

页数：14

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