Synthesis of novel push-pull fluorescent dyes-7-(diethylamino)furo[3,2-c]coumarin and 7-(diethylamino)thieno[3,2-c]coumarin derivatives

被引：17

作者：

Akchurin, Igor O. ^{[1
]}

Yakhutina, Anna I. ^{[1
]}

Bochkov, Andrei Y. ^{[1
]}

Solovjova, Natalya P. ^{[1
]}

Traven, Valerii F. ^{[1
]}

机构：

[1] D Mendeleev Univ Chem Technol Russia, RAS, Higher Chem Coll, Miusskaya Sq 9, Moscow 125047, Russia

来源：

HETEROCYCLIC COMMUNICATIONS | 2018年 / 24卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

coumarin; electron absorption spectra; fluorescence; push-pull dyes; SENSITIZED SOLAR-CELLS; REGIOSELECTIVE SYNTHESIS; COUMARIN DYES; DESIGN; PROBES;

D O I：

10.1515/hc-2017-0253

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel push-pull fluorescent dyes, 7-(diethyl-amino)furo[3,2-c]coumarin and 7-(diethylamino)thieno[3,2-c]coumarin derivatives, were designed and synthesized using formyl derivatives of furo-and thieno[3,2-c]coumarins as key intermediates. Electron absorption and emission spectra of the dyes were recorded in different solvents. The longest-wave bands in the electron absorption spectra of the dyes are suggested to be of push-pull nature.

引用

页码：85 / 91

页数：7

共 39 条

[1]

Ayyangar N. R., POLYCYCLIC COMPOUN 7

[2] Fluorescent polarity probes for identifying bovine serum albumin: Amplification effect of para-substituted benzene [J].

Bai, Hongyan ;

Qian, Junhong ;

Tian, Haiyu ;

Pan, Wenwen ;

Zhang, Lingyi ;

Zhang, Weibing .

DYES AND PIGMENTS, 2014, 103 :1-8

[3]

Bangar R. B., 1985, J PHOTOCHEM A, V85, P263

[4] NIR-fluorescent coumarin-fused BODIPY dyes with large Stokes shifts [J].

Bochkov, Andrei Y. ;

Akchurin, Igor O. ;

Dyachenko, Oleg A. ;

Traven, Valery F. .

CHEMICAL COMMUNICATIONS, 2013, 49 (99) :11653-11655

[5]

Brackman U., 1997, LAMDACHROME LASER DY, P153

[6] Synthesis and characterization of push-pull bithienylpyrrole NLOphores with enhanced hyperpolarizabilities [J].

Castro, M. Cidalia R. ;

Belsley, M. ;

Raposo, M. Manuela M. .

DYES AND PIGMENTS, 2016, 131 :333-339

[7] Structure, reactivity, and application of some triketone derivatives [J].

Chen, You-Sheng ;

Kuo, Pei-Yu ;

Shie, Tien-Lan ;

Yang, Ding-Yah .

TETRAHEDRON, 2006, 62 (40) :9410-9416

[8] Recent progress in second-order nonlinear optical polymers and dendrimers [J].

Cho, Min Ju ;

Choi, Dong Hoon ;

Sullivan, Philip A. ;

Akelaitis, Andrew J. P. ;

Dalton, Larry R. .

PROGRESS IN POLYMER SCIENCE, 2008, 33 (11) :1013-1058

[9] Studies of fluorescent dyes:: part 2.: An investigation of the synthesis and electronic spectral properties of substituted 3-(2′-benzimidazolyl)coumarins [J].

Christie, RM ;

Lui, CH .

DYES AND PIGMENTS, 2000, 47 (1-2) :79-89

[10] Et3N-Induced Demethylation-Annulation of 3-Alkynyl-4-methoxy-2-pyridones and Structurally Related Compounds in the Synthesis of Furan-Fused Heterocycles [J].

Conreaux, David ;

Belot, Sebastien ;

Desbordes, Philippe ;

Monteiro, Nuno ;

Balme, Genevieve .

JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (21) :8619-8622

← 1 2 3 4 →