Silver-Mediated Phosphonylation of C(sp2)-H Bonds with P-H Bonds: Direct C-H Functionalization of Ferrocenyl Anilides and Dialkyl Phosphites under Palladium- and Copper-Free Conditions

被引：7

作者：

Yu, Xiaoli ^{[1
]}

Ge, Bingyang ^{[1
]}

Zhang, Yaxuan ^{[1
]}

Wang, Xiaoli ^{[1
]}

Wang, Dawei ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, 1800 Lihu Rd, Wuxi 214122, Jiangsu, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 5卷 / 10期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

ferrocenyl derivatives; dialkyl phosphites; phosphonylation; radical reactions; silver; CROSS-COUPLING REACTIONS; CARBON-PHOSPHORUS FUNCTIONALIZATION; DIRECT REGIOSELECTIVE PHOSPHONATION; PLANAR-CHIRAL HETEROCYCLES; ONE-POT SYNTHESIS; ASYMMETRIC CATALYSIS; (E)-1-ALKENYLPHOSPHINE OXIDES; DIPHENYLPHOSPHINE OXIDE; PHOTOREDOX CATALYSIS; ARYLPROPIOLIC ACIDS;

D O I：

10.1002/ajoc.201600296

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A direct, silver-mediated C-H phosphonylation reaction of ferrocenyl anilides and dialkyl phosphites was developed. This methodology can tolerate a variety of functional groups and is free of palladium and copper. Moreover, mechanistic studies have revealed that the reaction pathway is of a radical type.

引用

页码：1253 / 1259

页数：7

共 24 条

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