Silver-Mediated Phosphonylation of C(sp2)-H Bonds with P-H Bonds: Direct C-H Functionalization of Ferrocenyl Anilides and Dialkyl Phosphites under Palladium- and Copper-Free Conditions

被引：7
|
作者：
Yu, Xiaoli [1 ]
Ge, Bingyang [1 ]
Zhang, Yaxuan [1 ]
Wang, Xiaoli [1 ]
Wang, Dawei [1 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Food Colloids & Biotechnol, 1800 Lihu Rd, Wuxi 214122, Jiangsu, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 5卷 / 10期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
ferrocenyl derivatives; dialkyl phosphites; phosphonylation; radical reactions; silver; CROSS-COUPLING REACTIONS; CARBON-PHOSPHORUS FUNCTIONALIZATION; DIRECT REGIOSELECTIVE PHOSPHONATION; PLANAR-CHIRAL HETEROCYCLES; ONE-POT SYNTHESIS; ASYMMETRIC CATALYSIS; (E)-1-ALKENYLPHOSPHINE OXIDES; DIPHENYLPHOSPHINE OXIDE; PHOTOREDOX CATALYSIS; ARYLPROPIOLIC ACIDS;
D O I：
10.1002/ajoc.201600296
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A direct, silver-mediated C-H phosphonylation reaction of ferrocenyl anilides and dialkyl phosphites was developed. This methodology can tolerate a variety of functional groups and is free of palladium and copper. Moreover, mechanistic studies have revealed that the reaction pathway is of a radical type.
引用
收藏
页码：1253 / 1259
页数：7
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