Functionalization of carbon nanotubes via nitrogen glow discharge

被引:71
作者
Khare, B [1 ]
Wilhite, P [1 ]
Tran, B [1 ]
Teixeira, E [1 ]
Fresquez, K [1 ]
Mvondo, DN [1 ]
Bauschlicher, C [1 ]
Meyyappan, M [1 ]
机构
[1] NASA, Ames Res Ctr, Ctr Nanotechnol, Moffett Field, CA 94035 USA
关键词
D O I
10.1021/jp0537254
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have exposed single-wall carbon nanotubes (SWCNTs) to microwave-generated N-2 plasma with the aim to functionalize the nanotubes. The results strongly depend on the distance between the discharge source and the sample, since nitrogen atoms generated can be lost due to recombination. No functionalization was observed when this distance was 7.0 cm. At intermediate distances (2.5 cm), the incorporation of nitrogen and oxygen onto the SWCNT was observed, while, at short distances (1 cm), products containing C N were also observed.
引用
收藏
页码:23466 / 23472
页数:7
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