Selective Oxidative Decarboxylation of Amino Acids to Produce Industrially Relevant Nitriles by Vanadium Chloroperoxidase

被引：52

作者：

But, Andrada ^{[1
,2
]}

Le Notre, Jerome ^{[2
]}

Scott, Elinor L. ^{[2
]}

Wever, Ron ^{[3
]}

Sanders, Johan P. M. ^{[2
]}

机构：

[1] Politehn Univ Timisoara, Ind Chem & Environm Engn Fac, Timisoara 300006, Romania

[2] Wageningen Univ, Chair Biobased Commod Chem, NL-6700 AA Wageningen, Netherlands

[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1090 GD Amsterdam, Netherlands

来源：

CHEMSUSCHEM | 2012年 / 5卷 / 07期

关键词：

amino acids; biomass; enzyme catalysis; halides; oxidation; FUNGUS CURVULARIA-INAEQUALIS; RENEWABLE CHEMICALS; GLUTAMIC-ACID; BIOMASS; BROMOPEROXIDASE; BROMINATION; CONVERSION; ENZYME;

D O I：

10.1002/cssc.201200098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Industrial nitriles from biomass: Vanadium-chloroperoxidase is successfully used to transform selectively glutamic acid into 3-cyanopropanoic acid, a key intermediate for the synthesis of bio-succinonitrile and bio-acrylonitrile, by using a catalytic amount of a halide salt. This clean oxidative decarboxylation can be applied to mixtures of amino acids obtained from plant waste streams, leading to easily separable nitriles. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1199 / 1202

页数：4

共 35 条

[1]

[Anonymous], 2009, OFFICIAL J EUROPEAN, V140

[2]

[Anonymous], 2009, Official Journal of the European Union, VL140/16, Patent No. [9527046, WO 95/27046]

[3] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[4] Mechanistic considerations of the vanadium haloperoxidases [J].

Butler, A .

COORDINATION CHEMISTRY REVIEWS, 1999, 187 :17-35

[5] Vanadium haloperoxidase-catalyzed bromination and cyclization of terpenes [J].

Carter-Franklin, JN ;

Parrish, JD ;

Tschirret-Guth, RA ;

Little, RD ;

Butler, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (13) :3688-3689

[6] The renewable chemicals industry [J].

Christensen, Claus Hviid ;

Rass-Hansen, Jeppe ;

Marsden, Charlotte C. ;

Taarning, Esben ;

Egeblad, Kresten .

CHEMSUSCHEM, 2008, 1 (04) :283-289

[7] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

[8]

Deike V., 1996, Raw Material Compendium

[9] Conversion of biomass to selected chemical products [J].

Gallezot, Pierre .

CHEMICAL SOCIETY REVIEWS, 2012, 41 (04) :1538-1558

[10]

Gribble GW., 2010, NATURALLY OCCURRING

← 1 2 3 4 →