Structure and magnetism of a Mn(III)-Mn(II)-Mn(II)-Mn(III) chain complex

被引：8

作者：

Uhrecky, Robert ^{[1
]}

Moncol, Jan ^{[1
]}

Koman, Marian ^{[1
]}

Titis, Jan ^{[2
]}

Boca, Roman ^{[2
]}

机构：

[1] Slovak Univ Technol Bratislava, Inst Inorgan Chem, FCHPT, Bratislava 81237, Slovakia

[2] Univ SS Cyril & Methodius, Dept Chem, FPV, Trnava 91701, Slovakia

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 26期

关键词：

CRYSTAL-STRUCTURE; PYRIDINE-2,6-DICARBOXYLIC ACID; MANGANESE(II) COMPLEXES; HYDROGEN-PRODUCTION; CHELIDAMIC ACID; FRAMEWORK; CATALYSTS; OXYGEN; 1D;

D O I：

10.1039/c3dt50940k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel tetranuclear manganese(II/III) complex with anions of pyridine-2,6-dicarboxylic acid (dipicolinic acid) has been synthesised and magneto-structurally characterised. The crystal structure of [Mn-II Mn-2(III) (2)-(dipic)(6)(H2O)(4)].2CH(3)OH . 4H(2)O has been determined by single-crystal X-ray diffraction. The tetranuclear complex molecule [Mn-II Mn-2(III) (2)(dipic)(6)(H2O)(4)] is centrosymmetric and two manganese(II) and two manganese(III) atoms are bridged by four dipicolinate ligands. The complex molecules and uncoordinated water and methanol molecules are connected through hydrogen bonds and they form a 3D supramolecular hydrogen-bonding network.

引用

页码：9490 / 9494

页数：5

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