Thermophysical properties of aqueous NaOH-H2O solutions at high concentrations

被引:33
作者
Olsson, J [1 ]
Jernqvist, A [1 ]
Aly, G [1 ]
机构
[1] LUND UNIV,DEPT CHEM ENGN 1,S-22100 LUND,SWEDEN
关键词
absorption; density; enthalpy; heat pump; sodium hydroxide; vapor pressure; viscosity;
D O I
10.1007/BF02575133
中图分类号
O414.1 [热力学];
学科分类号
摘要
The working fluids, used in the majority of all mechanical heat pumps, are expected to be phased out within some few yeats due to their contribution to the stratospheric ozone depletion and global warming. Absorption heat pumps and transformers are receiving a new renaissance in the field of heating, refrigeration, air-conditioning, and heat recovery. Sodium hydroxide solutions are more propitious to the pulp and paper industry compared to other working pairs. Novel correlations have been developed to compute the vapor pressure, density, enthalpy, and viscosity of sodium hydroxide solutions. These correlations cover the most extensive range of validity ever proposed: 273-473 K for temperatures and 0.2-1 kg water per kg solution for concentrations.
引用
收藏
页码:779 / 793
页数:15
相关论文
共 22 条
[1]  
ABRAHAMSSON K, 1994, P INT ABS HEAT P AES, V31, P295
[2]  
ABRAHAMSSON K, 1993, THESIS LUND U LUND S
[3]  
ABRAHAMSSON K, 1997, IN PRESS INT J ENERG
[4]  
ABRAHAMSSON K, 1992, THESIS LUND U LUND S, V6, P9
[5]  
ACKERMANN T, 1957, DISCUSS FARADAY SOC, V24, P180
[6]   Thermodynamics of concentrated aqueous solutions of sodium hydroxide [J].
Akerlof, G ;
Kegeles, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :620-640
[7]   WATER-VAPOR PARTIAL PRESSURES AND WATER ACTIVITIES IN POTASSIUM AND SODIUM-HYDROXIDE SOLUTIONS OVER WIDE CONCENTRATION AND TEMPERATURE RANGES [J].
BALEJ, J .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1985, 10 (04) :233-243
[8]  
BARON NM, 1967, J APPL CHEM-USSR, V40, P652
[9]   Specific heats of sodium hydroxide solution [J].
Bertetti, JW ;
McCabe, WL .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1936, 28 :375-378
[10]   Sodium hydroxide solutions - Heat of dilution at 68 degrees F. [J].
Bertetti, JW ;
McCabe, WL .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1936, 28 :247-248