Aminolysis of Epoxides in Ionic Liquid 1-Ethylpyridinium Trifluoroacetate as Green and Efficient Reaction Medium

被引：13
|
作者：
Malhotra, Sanjay V. [1 ]
Andal, Richard P. [1 ]
Kumar, Vineet [1 ]
机构：
[1] New Jersey Inst Technol, Dept Chem & Environm Sci, Newark, NJ 07102 USA
来源：
SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 23期
关键词：
-Amino alcohols; aminolysis; epoxides; ionic liquids;
D O I：
10.1080/00397910802323056
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aminolysis of epoxides has been carried out using the ionic liquid 1-ethylpyridinium trifluoroacetate ([EtPy][TFA]) as reaction medium. The reactions went smoothly under mild conditions without any catalyst to afford corresponding -aminoalcohols in high conversions. Moreover, further enhancement in the conversions was observed when AlCl3 was used as Lewis acid catalyst.
引用
收藏
页码：4160 / 4169
页数：10
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