Intramolecular vibrational redistribution: from high-resolution spectra to real-time dynamics

被引：36

作者：

Makarov, A. A. ^{[1
]}

Malinovsky, A. L. ^{[1
]}

Ryabov, E. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Spect, Moscow 142190, Russia

来源：

PHYSICS-USPEKHI | 2012年 / 55卷 / 10期

基金：

俄罗斯基础研究基金会;

关键词：

INFRARED DOUBLE-RESONANCE; C-H STRETCH; EXTENSIVELY PERTURBED SPECTRA; MOLECULAR EIGENSTATE SPECTRUM; MULTIPLE-PHOTON ABSORPTION; LARGE POLYATOMIC-MOLECULES; UNIMOLECULAR GAS REACTIONS; =CH2 HYDRIDE STRETCH; QUANTUM ENERGY-FLOW; QUASI-CONTINUUM;

D O I：

10.3367/UFNe.0182.201210e.1047

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Intramolecular vibrational redistribution is a fundamental phenomenon observed in polyatomic molecules when sufficiently excited vibrationally. In this paper, results mostly from the last two decades of research on this subject are summarized, obtained either from infrared spectroscopy with a resolution of as high as 10(-4) cm(-1) or, in a different approach, by using various pump-probe schemes with a temporal resolution from dozens of picoseconds to subpicoseconds.

引用

页码：977 / 1007

页数：31

共 351 条

[1] FLUORESCENCE AND STIMULATED-EMISSION S1-]SO SPECTRA OF ACETYLENE - REGULAR AND ERGODIC REGIONS [J].