Large scale electrochemical synthesis of high quality carbon nanodots and their photocatalytic property

被引:680
作者
Ming, Hai
Ma, Zheng
Liu, Yang [1 ]
Pan, Keming
Yu, Hang
Wang, Fang
Kang, Zhenhui
机构
[1] Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou 215123, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
VISIBLE-LIGHT; QUANTUM DOTS; NANOPARTICLES; GRAPHITE; GRAPHENE; WATER; PHOTOLUMINESCENCE; RECOMBINATION; DEGRADATION; FABRICATION;
D O I
10.1039/c2dt30985h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
High quality carbon nanodots (C-dots) with high purity were synthesized through a mild, one-step electrochemical approach, without the assistance of any chemicals but only pure water. This high productivity method makes the synthetic process of C-dots synthesis both economical as well as environment-friendly. The as prepared C-dots are predominantly multi-layer graphene oxide, with luminescence and high up-conversion photoluminescence (emission of light at shorter wavelengths than the excitation wavelength). Meanwhile, C-dots showed peroxidise mimetic function and visible-light-sensitive photocatalytic activity for methyl orange degradation. In addition, a novel photocatalyst (TiO2/C-dots) was obtained by combining C-dots with TiO2 through an easy hydrothermal method. Remarkably, TiO2/C-dots exhibited an excellent visible-light photocatalytic activity.
引用
收藏
页码:9526 / 9531
页数:6
相关论文
共 30 条
  • [1] Horseradish peroxidase immobilized on aluminum-pillaredinterlayered clay for the catalytic oxidadon of phenolic wastewater
    Cheng, J
    Yu, SM
    Zuo, P
    [J]. WATER RESEARCH, 2006, 40 (02) : 283 - 290
  • [2] Metal-free activation of H2O2 by g-C3N4 under visible light irradiation for the degradation of organic pollutants
    Cui, Yanjuan
    Ding, Zhengxin
    Liu, Ping
    Antonietti, Markus
    Fu, Xianzhi
    Wang, Xinchen
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (04) : 1455 - 1462
  • [3] Blue Photoluminescence from Chemically Derived Graphene Oxide
    Eda, Goki
    Lin, Yun-Yue
    Mattevi, Cecilia
    Yamaguchi, Hisato
    Chen, Hsin-An
    Chen, I-Sheng
    Chen, Chun-Wei
    Chhowalla, Manish
    [J]. ADVANCED MATERIALS, 2010, 22 (04) : 505 - +
  • [4] Raman spectrum of graphene and graphene layers
    Ferrari, A. C.
    Meyer, J. C.
    Scardaci, V.
    Casiraghi, C.
    Lazzeri, M.
    Mauri, F.
    Piscanec, S.
    Jiang, D.
    Novoselov, K. S.
    Roth, S.
    Geim, A. K.
    [J]. PHYSICAL REVIEW LETTERS, 2006, 97 (18)
  • [5] Water soluble carbon nanoparticles: Hydrothermal synthesis and excellent photoluminescence properties
    He, Xiaodie
    Li, Haitao
    Liu, Yang
    Huang, Hui
    Kang, Zhenhui
    Lee, Shuit-Tong
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2011, 87 (02) : 326 - 332
  • [6] Photoluminescent Fe3O4/carbon nanocomposite with magnetic property
    He, Xiaodie
    Liu, Yang
    Li, Haitao
    Huang, Hui
    Liu, Jinglin
    Kang, Zhenhui
    Lee, Shuit-Tong
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 356 (01) : 107 - 110
  • [7] Radiative and nonradiative recombination in polymerlike α-C:H films
    Heitz, T
    Godet, C
    Bourée, JE
    Drévillon, B
    Conde, JP
    [J]. PHYSICAL REVIEW B, 1999, 60 (08) : 6045 - 6052
  • [8] Controllable fabrication of carbon nanotube and nanobelt with a polyoxometalate-assisted mild hydrothermal process
    Kang, ZH
    Wang, EB
    Mao, BD
    Su, ZM
    Lei, G
    Lian, SY
    Lin, X
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (18) : 6534 - 6535
  • [9] The activation characteristics of the decomposition of H2O2 on palladium-carbon catalysts
    Lapko, V. F.
    Gerasimyuk, I. P.
    Kuts', V. S.
    Tarasenko, Yu. A.
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2010, 84 (06) : 934 - 940
  • [10] Processable aqueous dispersions of graphene nanosheets
    Li, Dan
    Mueller, Marc B.
    Gilje, Scott
    Kaner, Richard B.
    Wallace, Gordon G.
    [J]. NATURE NANOTECHNOLOGY, 2008, 3 (02) : 101 - 105