Intramolecularly Coordinated Group 14 and 15 Chalcogenites

被引：26

作者：

Mairychova, Barbora ^{[1
]}

Svoboda, Tomas ^{[1
]}

Erben, Milan ^{[1
]}

Ruzicka, Ales ^{[1
]}

Dostal, Libor ^{[1
]}

Jambor, Roman ^{[1
]}

机构：

[1] Univ Pardubice, Dept Gen & Inorgan Chem, Fac Chem Technol, CZ-53210 Pardubice, Czech Republic

来源：

ORGANOMETALLICS | 2013年 / 32卷 / 01期

关键词：

ORGANIC-INORGANIC NANOCOMPOSITES; SELENITE-CARBOXYLATE COMPOUNDS; BOND COVALENT RADII; CRYSTAL-STRUCTURES; MIXED-OXIDE; STRUCTURAL-CHARACTERIZATION; SELECTIVE OXIDATION; MOLECULAR DESIGN; ETHYLENE-OXIDE; BISMUTH OXIDE;

D O I：

10.1021/om3009553

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of N -> M intramolecularly coordinated group 14 and 15 chalcogenites is reported. The N -> Sn intramolecularly coordinated organotin(IV) carbonate L(Ph)SnCO3 (1), where L is the N,C,N-chelating ligand 2,6-(Me2NCH2)(2)C6H3-, reacts with SO2 and SeO2 to provide the organotin(IV) sulfite L(Ph)SnSO3 (4) and selenite [L(Ph)SnSeO3](2) (5), respectively. Treatment of [LSbO](2) (2) and [LBiO](2) (3) with SeO2 provided the organoantimony and bismuth selenites LSbSeO3 (6) and [LBiSeO3](3) (7), respectively. Compounds 5-7 are rare examples of mixed element oxides with well-defined stoichiometry MSeO3 (M = Sn, Sb, Bi). Compounds 4-7 were characterized by means of elemental analyses, H-1, C-13, Se-77, and Sn-119 NMR spectroscopies, IR spectroscopy, and single-crystal X-ray diffraction analysis.

引用

页码：157 / 163

页数：7

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