Pressure-accelerated copper-free cycloaddition of azide and alkyne groups pre-organized in the crystalline state at room temperature

被引：26

作者：

Chen, Hao ^{[1
]}

Ni, Ben-Bo ^{[1
]}

Gao, Fan ^{[1
]}

Ma, Yuguo ^{[1
]}

机构：

[1] Peking Univ, Coll Chem, Minist Educ,Key Lab Polymer Chem & Phys, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 10期

基金：

中国国家自然科学基金;

关键词：

PHENYL-PERFLUOROPHENYL STACKING; SOLID-STATE; CLICK CHEMISTRY; PHASE-BEHAVIOR; PI-STACKING; BENZENE; POLYMERIZATION; INHIBITORS; COMPLEXES;

D O I：

10.1039/c2gc36069a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have designed a supramolecular system to pre-organize the azide and alkyne functional groups via electrostatic and arene-perfluoroarene interactions. After pre-organization, high pressure was applied to accelerate the copper-free cycloaddition of the azide and alkyne groups in the crystalline state.

引用

页码：2703 / 2705

页数：3

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