Triazenide complexes of iridium. Evidence for [Ir(η1-N3Ph2)(HN3Ph2)(1,5-cod)], structures of [Ir2(μ-OMe)2(1,5-cod)2], [Ir2(μ-N3Ph2)2(1,5-cod)2], [Ir(η2-N3Ph2)(H)(SiPh3)(1,5-cod)], [Ir(η2-N3Ph2)(H)(SnPh3)(1,5-cod)] and [Ir(η2-N3Ph2)(SC6F5)2(1,5-cod)]

被引：5
|
作者：
Carlton, Laurence [1 ]
Nyoni, Michelle S. [1 ]
Fernandes, Manuel A. [1 ]
机构：
[1] Univ Witwatersrand, Inst Mol Sci, Sch Chem, Johannesburg, South Africa
来源：
POLYHEDRON | 2016年 / 119卷
关键词：
Iridium; Triazenide; Triphenylsilyl; Triphenyltin; Pentafluorophenylthiolate; REDUCTION-OXIDATION PROPERTIES; RAY CRYSTAL-STRUCTURE; ORGANOTRANSITION-METAL COMPLEXES; ROW TRANSITION-METALS; PLATINUM METALS; DINUCLEAR PALLADIUM(I); BIPYRIDYL COMPLEXES; BRIDGED RHODIUM; DERIVATIVES; RUTHENIUM;
D O I：
10.1016/j.poly.2016.03.022
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [Ir-2(mu-OMe)(2)(1,5-cod)(2)] with diphenyltriazene gives a product, formulated as [Ir(eta(1)-N3Ph2)(HN3Ph2)(1,5-cod)] on, the basis of NMR data, which dimerises slowly in solution forming [Ir-2(mu-N3Ph2)(2)(1,5-cod)(2)] and which reacts with SiHPh3, SnHPh3 and C6F5SH to give [Ir(eta(2)-N3Ph2)(H)(SiPh3)(1,5-cod)], [Ir(eta(2)-N3Ph2)(H)(SnPh3)(1,5-cod)] and [Ir(eta(2)-N3Ph2)(SC6F5)(2)(1,5-cod)] respectively. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：194 / 201
页数：8
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