Correlation of x-ray absorption and x-ray photoemission spectroscopies in amorphous carbon nitride

被引：100

作者：

Ripalda, JM ^{[1
]}

Román, E

Díaz, N

Galán, L

Montero, I

Comelli, G

Baraldi, A

Lizzit, S

Goldoni, A

Paolucci, G

机构：

[1] Univ Autonoma Madrid, Dept Fis Aplicada, E-28049 Madrid, Spain

[2] CSIC, Inst Ciencia Mat, E-28049 Madrid, Spain

[3] Sincrotrone Trieste SCpA, I-34012 Trieste, Italy

[4] INFM, Lab TASC, I-34012 Trieste, Italy

来源：

PHYSICAL REVIEW B | 1999年 / 60卷 / 06期

关键词：

D O I：

10.1103/PhysRevB.60.R3705

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The nature of bonding in amorphous carbon nitride was studied by synchrotron-radiation photoemission spectroscopy and near-edge x-ray-absorption fine structure, The experimental data are compared with theoretical calculations of chemical shifts, and the relative importance of initial and final state effects is discussed. Bond lengths are determined from the position of the sigma* resonance and the obtained results suggest sp(2) hybridization. The experimental and theoretical evidence presented in this paper supports another interpretation of the photoemission spectra of amorphous carbon nitride. [S0163-1829(99)50230-0].

引用

页码：R3705 / R3708

页数：4

共 16 条

[1] Equivalent-core calculation of core-level relaxation energies in photoelectron spectroscopy: A molecular-orbital approach [J].

Chen, Y ;

Zhuang, G ;

Ross, PN ;

Van Hove, MA ;

Fadley, CS .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (16) :6527-6532

[2] CALCULATION OF BULK MODULI OF DIAMOND AND ZINCBLENDE SOLIDS [J].

COHEN, ML .

PHYSICAL REVIEW B, 1985, 32 (12) :7988-7991

[3]

Frisch M. J., 2004, GAUSSIAN 03

[4] An X-ray photoelectron spectroscopy study of carbon nitride films grown by low energy ion implantation [J].

Galan, L ;

Montero, I ;

Rueda, F .

SURFACE & COATINGS TECHNOLOGY, 1996, 83 (1-3) :103-108

[5] PREDICTION OF NEW LOW COMPRESSIBILITY SOLIDS [J].

LIU, AY ;

COHEN, ML .

SCIENCE, 1989, 245 (4920) :841-842

[6] CARBON NITRIDE DEPOSITED USING ENERGETIC SPECIES - A 2-PHASE SYSTEM [J].

MARTON, D ;

BOYD, KJ ;

ALBAYATI, AH ;

TODOROV, SS ;

RABALAIS, JW .

PHYSICAL REVIEW LETTERS, 1994, 73 (01) :118-121

[7] EXPERIMENTAL REALIZATION OF THE COVALENT SOLID CARBON NITRIDE [J].

NIU, CM ;

LU, YZ ;

LIEBER, CM .

SCIENCE, 1993, 261 (5119) :334-337

[8] EVOLUTION OF NITROGEN FUNCTIONALITIES IN CARBONACEOUS MATERIALS DURING PYROLYSIS [J].

PELS, JR ;

KAPTEIJN, F ;

MOULIJN, JA ;

ZHU, Q ;

THOMAS, KM .

CARBON, 1995, 33 (11) :1641-1653

[9]

SPAETH C, IN PRESS DIAMOND REL

[10]

Stohr J, 1992, NEXAFS SPECTROSCOPY

← 1 2 →