Dodecanuclear Hexagonal-Prismatic M12L18 Coordination Cages by Subcomponent Self-assembly

被引：41
|
作者：
Sham, Kiu-Chor [1 ]
Yiu, Shek-Man [1 ]
Kwong, Hoi-Lun [1 ]
机构：
[1] City Univ Hong Kong, Dept Biol & Chem, Kowloon, Hong Kong, Peoples R China
来源：
INORGANIC CHEMISTRY | 2013年 / 52卷 / 10期
关键词：
CHEMISTRY; COMPLEXES; POLYHEDRA; DESIGN;
D O I：
10.1021/ic400665m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Dodecanuclear hexagonal-prismatic M12L18 cages were prepared by a subcomponent self-assembly process with commercially available pyridinecarboxaldehyde, m-xylenediamine, and cadmium(II) perchlorate or manganese(II) perchlorate. The NMR spectrum of the Cd cage shows that there are three independent ligand sets, and the X-ray crystal structure of the Mn cage reveals that the structure has both fac-Delta- and mer-Lambda-configured metal centers in a 1:1 ratio. The cage structure also has a large cavity that contains five perchlorate anions.
引用
收藏
页码：5648 / 5650
页数：3
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