Tailoring Intercalant Assemblies at the Graphene-Metal Interface

被引:2
作者
Halle, Johannes [1 ]
Neel, Nicolas [1 ]
Kroeger, Joerg [1 ]
机构
[1] Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
关键词
BORON-NITRIDE NANOMESH; EPITAXIAL GRAPHENE; SURFACE-STATE; BILAYER GRAPHENE; ADSORPTION; RECONSTRUCTION; GROWTH; ENERGY; CS; MOLECULES;
D O I
10.1021/acs.langmuir.8b03879
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The influence of graphene on the assembly of intercalated material is studied using low-temperature scanning tunneling microscopy. Intercalation of Pt under monolayer graphene on Pt(111) induces a substrate reconstruction that is qualitatively different from the lattice rearrangement induced by metal deposition on Pt(111) and, specifically, the homoepitaxy of Pt. Alkali metals Cs and Li are used as intercalants for monolayer and bilayer graphene on Ru(0001). Atomically resolved topographic data reveal that at elevated alkali metal coverage (2 x 2)Cs and (1 x 1)Li intercalant structures form with respect to the graphene lattice.
引用
收藏
页码:2554 / 2560
页数:7
相关论文
共 117 条
[81]   Two Distinct Phases of Bilayer Graphene Films on Ru(0001) [J].
Papagno, Marco ;
Pacile, Daniela ;
Topwal, Dinesh ;
Moras, Paolo ;
Sheverdyaeva, Polina Makarovna ;
Natterer, Fabian Donat ;
Lehnert, Anne ;
Rusponi, Stefano ;
Dubout, Quentin ;
Calleja, Fabian ;
Frantzeskakis, Emmanouil ;
Pons, Stephane ;
Fujii, Jun ;
Vobornik, Ivana ;
Grioni, Marco ;
Carbone, Carlo ;
Brune, Harald .
ACS NANO, 2012, 6 (10) :9299-9304
[82]   Large Band Gap Opening between Graphene Dirac Cones Induced by Na Adsorption onto an Ir Superlattice [J].
Papagno, Marco ;
Rusponi, Stefano ;
Sheverdyaeva, Polina Makarovna ;
Vlaic, Sergio ;
Etzkorn, Markus ;
Pacile, Daniela ;
Moras, Paolo ;
Carbone, Carlo ;
Brune, Harald .
ACS NANO, 2012, 6 (01) :199-204
[83]   Li adsorption versus graphene intercalation on Ir(111): From quenching to restoration of the Ir surface state [J].
Pervan, P. ;
Lazic, P. ;
Petrovic, M. ;
Rakic, I. Srut ;
Pletikosic, I. ;
Kralj, M. ;
Milun, M. ;
Valla, T. .
PHYSICAL REVIEW B, 2015, 92 (24)
[84]   The mechanism of caesium intercalation of graphene [J].
Petrovic, M. ;
Rakic, I. Srut ;
Runte, S. ;
Busse, C. ;
Sadowski, J. T. ;
Lazic, P. ;
Pletikosic, I. ;
Pan, Z. -H. ;
Milun, M. ;
Pervan, P. ;
Atodiresei, N. ;
Brako, R. ;
Sokcevic, D. ;
Valla, T. ;
Michely, T. ;
Kralj, M. .
NATURE COMMUNICATIONS, 2013, 4
[85]   Direct capture and electrostatic repulsion in the self-assembly of rare-earth atom superlattices on graphene [J].
Pivetta, Marina ;
Rusponi, Stefano ;
Brune, Harald .
PHYSICAL REVIEW B, 2018, 98 (11)
[86]   Supramolecular Assemblies Formed on an Epitaxial Graphene Superstructure [J].
Pollard, Andrew J. ;
Perkins, Edward W. ;
Smith, Nicholas A. ;
Saywell, Alex ;
Goretzki, Gudrun ;
Phillips, Anna G. ;
Argent, Stephen P. ;
Sachdev, Hermann ;
Mueller, Frank ;
Huefner, Stefan ;
Gsell, Stefan ;
Fischer, Martin ;
Schreck, Matthias ;
Osterwalder, Juerg ;
Greber, Thomas ;
Berner, Simon ;
Champness, Neil R. ;
Beton, Peter H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (10) :1794-1799
[87]   Controlling graphene corrugation on lattice-mismatched substrates [J].
Preobrajenski, A. B. ;
Ng, May Ling ;
Vinogradov, A. S. ;
Martensson, N. .
PHYSICAL REVIEW B, 2008, 78 (07)
[88]  
Profeta G, 2012, NAT PHYS, V8, P131, DOI [10.1038/NPHYS2181, 10.1038/nphys2181]
[89]   Reconstruction of Pt(111) and domain patterns on close-packed metal surfaces [J].
Pushpa, R ;
Narasimhan, S .
PHYSICAL REVIEW B, 2003, 67 (20)
[90]   Epitaxial growth of large-area bilayer graphene on Ru(0001) [J].
Que, Yande ;
Xiao, Wende ;
Fei, Xiangmin ;
Chen, Hui ;
Huang, Li ;
Du, S. X. ;
Gao, H. -J. .
APPLIED PHYSICS LETTERS, 2014, 104 (09)