Tailoring Intercalant Assemblies at the Graphene-Metal Interface

被引:2
作者
Halle, Johannes [1 ]
Neel, Nicolas [1 ]
Kroeger, Joerg [1 ]
机构
[1] Tech Univ Ilmenau, Inst Phys, D-98693 Ilmenau, Germany
关键词
BORON-NITRIDE NANOMESH; EPITAXIAL GRAPHENE; SURFACE-STATE; BILAYER GRAPHENE; ADSORPTION; RECONSTRUCTION; GROWTH; ENERGY; CS; MOLECULES;
D O I
10.1021/acs.langmuir.8b03879
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The influence of graphene on the assembly of intercalated material is studied using low-temperature scanning tunneling microscopy. Intercalation of Pt under monolayer graphene on Pt(111) induces a substrate reconstruction that is qualitatively different from the lattice rearrangement induced by metal deposition on Pt(111) and, specifically, the homoepitaxy of Pt. Alkali metals Cs and Li are used as intercalants for monolayer and bilayer graphene on Ru(0001). Atomically resolved topographic data reveal that at elevated alkali metal coverage (2 x 2)Cs and (1 x 1)Li intercalant structures form with respect to the graphene lattice.
引用
收藏
页码:2554 / 2560
页数:7
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