One-Pot Covalent Functionalization of 2D Black Phosphorus by Anionic Ring Opening Polymerization

被引:8
作者
Bawadkji, Obida [1 ]
Cherri, Mariam [1 ]
Schaefer, Andreas [1 ]
Herziger, Svenja [2 ]
Nickl, Philip [1 ,3 ]
Achazi, Katharina [1 ]
Donskyi, Ievgen S. [1 ,3 ]
Adeli, Mohsen [4 ]
Haag, Rainer [1 ]
机构
[1] Free Univ Berlin, Inst Chem & Biochem, Takustr 3, D-14195 Berlin, Germany
[2] Free Univ Berlin, Inst Chem & Biochem, Forschungszentrum Elektronenmikroskopie & Core Fa, Fabeckstr 36a, D-14195 Berlin, Germany
[3] BAM Fed Inst Mat Sci & Testing, Div Surface Anal & Interfacial Chem, Eichen 44-46, D-12205 Berlin, Germany
[4] Lorestan Univ, Fac Sci, Dept Chem, Khorramabad 6815144316, Iran
关键词
2D nanomaterials; amphiphilicity; black phosphorus; hyperbranched polyglycerol; water dispersibility; HYPERBRANCHED POLYGLYCEROLS; BIOLOGICAL EVALUATION; PHOTOTHERMAL THERAPY; NANOPARTICLES; NANOSHEETS; SURFACE; NANOMATERIALS; PASSIVATION; STABILITY; PLATFORM;
D O I
10.1002/admi.202201245
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, a one-pot approach for the covalent functionalization of few-layer black phosphorus (BP) by anionic ring opening polymerization of glycidol to obtain multifunctional BP-polyglycerol (BP-PG) with high amphiphilicity for near-infrared-responsive drug delivery and biocompatibility is reported. Straightforward synthesis in combination with exceptional biological and physicochemical properties designates functionalized BP-PG as a promising candidate for a broad range of biomedical applications.
引用
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页数:8
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