Synthesis and structural characterization of BINOL-modified chiral polyoxometalates

被引：14

作者：

Ishimoto, Ryo ^{[1
]}

Kamata, Keigo ^{[1
]}

Suzuki, Kosuke ^{[1
]}

Yamaguchi, Kazuya ^{[1
]}

Mizuno, Noritaka ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 24期

关键词：

SPONTANEOUS RESOLUTION; ASYMMETRIC ADDITION; CIRCULAR-DICHROISM; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; METAL-OXIDE; KEGGIN-TYPE; COMPLEXES; TITANIUM; OXIDATION;

D O I：

10.1039/c5dt01338k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral ligand-modified polyoxometalates (POMs) were successfully synthesized by the introduction of BINOL into the dititanium-substituted POM in an organic medium and characterized by X-ray crystallography, spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the solution state and showed catalytic activity for asymmetric oxidation of thioanisole.

引用

页码：10947 / 10951

页数：5

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