Synthesis and structural characterization of BINOL-modified chiral polyoxometalates

被引：14
作者：
Ishimoto, Ryo [1 ]
Kamata, Keigo [1 ]
Suzuki, Kosuke [1 ]
Yamaguchi, Kazuya [1 ]
Mizuno, Noritaka [1 ]
机构：
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 24期
关键词：
SPONTANEOUS RESOLUTION; ASYMMETRIC ADDITION; CIRCULAR-DICHROISM; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; METAL-OXIDE; KEGGIN-TYPE; COMPLEXES; TITANIUM; OXIDATION;
D O I：
10.1039/c5dt01338k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chiral ligand-modified polyoxometalates (POMs) were successfully synthesized by the introduction of BINOL into the dititanium-substituted POM in an organic medium and characterized by X-ray crystallography, spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the solution state and showed catalytic activity for asymmetric oxidation of thioanisole.
引用
收藏
页码：10947 / 10951
页数：5
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