Synthesis of a novel host-calix[4]arene derivative and its application to recognition analysis of lanthanide ions

被引：0
作者：
Liu Zhi-Lian
Liang Zhi
Jiang Lin
Gao Yun-Hua [1 ]
机构：
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100101, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2006年 / 27卷 / 05期
关键词：
spirobenzopyrans; calixarene derivatives; metal ion; recognition;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of the novel host compound carrying two spirobenzopyran groups was described. Its structure was confirmed by H-1 NMR, IR and elemental analysis'. It was shown that the novel host can recognize lanthanide ions selectively with significant spectral shifts in visible region and enhanced absorbance. Thus, the compound can be used to recognize lanthanide ions by naked eyes. The selectivity was relative to size-fit effect. The order of spectral changes was Yb3+ > Er3+ > Gd3+ > Dy3+ > Eu3+ > Pr3+ > La3+, which is opposite to the order of the radii of lanthanide ions. We discussed the possible binding mechanism with analyzing the different UV-Vis spectral changes resulted by addition of the investigated ions.
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页码：888 / 890
页数：3
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