THE TAUTOMERISM OF PYRAZOLINES (DIHYDROPYRAZOLES)

被引：7
作者：
Alkorta, I. [1 ]
Elguero, J. [1 ]
机构：
[1] Inst Quim Med CSIC, E-28006 Madrid, Spain
来源：
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2015年 / 60卷 / 02期
关键词：
pyrazolines; dihydropyrazoles; rearrangement; NMR; DFT calculations; GIAO; MOLECULAR-ORBITAL METHODS; COUPLING-CONSTANTS; CHEMICAL-SHIFTS; DECOMPOSITION; STEREOCHEMISTRY;
D O I：
10.4067/S0717-97072015000200022
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The exception to the rule that Delta(3)-pyrazolines are not stable unless both nitrogen atoms are substituted that has been recently published, Tetrahedron Lett. 55, 2208, (2014), has been proved false. By means of GIAO/B3LYP/6-311++G(d,p) calculations, it has been shown that the product is a pyrazole formed by rearrangement.
引用
收藏
页码：2966 / 2970
页数：5
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