Adsorption desalination of chloride ions on composite natural-synthetic materials: An approach for the reduction of chlorine corrosion in electrodeionization units

被引:10
作者
Al-Rawajfeh, Aiman E. [1 ,2 ]
Al-Shamaileh, Ehab M. [3 ,4 ]
Al-Whoosh, Khaldoon [1 ]
Al-Ma'abrah, Ala'a [1 ]
Al-Zorqan, Ramzi [1 ]
Zanoon, Rana [1 ]
Rawajfeh, Khalid [3 ]
Al-Jufout, Saleh [1 ]
机构
[1] Tafila Tech Univ, POB 179, Tafila 66110, Jordan
[2] JAEC, Amman, Jordan
[3] Univ Jordan, Amman 11942, Jordan
[4] Salman bin Abdulaziz Univ, Al Kharj 11942, Saudi Arabia
关键词
Electrodeionization; Chlorine gas release; Corrosion; Adsorption desalination; Natural materials; TRIPOLI;
D O I
10.1016/j.jiec.2013.02.035
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The release of chlorine in the electrodeionization (EDI) unit causes corrosion in the EDI unit, damaging ion exchange membranes and creating a safety risk for the workers. In this work, adsorption desalination of Cl- ions on low-cost composite synthetic-natural Jordanian materials were investigated as an approach to prevent the release of corrosive chlorine gas at the positive electrode. The percentage removal reaches 25% at 25 min shaking time to 55% at 120 min, in a single batch experiment. The values of Delta H-0, Delta S-0, and Delta G(0) indicate the favorability of physisorption. Zeolite and Pozzolana represent potential adsorbents of chloride. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights
引用
收藏
页码:1895 / 1902
页数:8
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