Enhanced electrochemical performance of MnO2/NiO nanocomposite for supercapacitor electrode with excellent cycling stability

被引:92
作者
Racik, K. Mohamed [1 ,2 ]
Guruprasad, K. [3 ]
Mahendiran, M. [1 ,2 ]
Madhavan, J. [1 ]
Maiyalagan, T. [3 ]
Raj, M. Victor Antony [1 ,2 ]
机构
[1] Loyola Coll, Dept Phys, Chennai, Tamil Nadu, India
[2] Loyola Coll, LIFE, Chennai, Tamil Nadu, India
[3] SRM Inst Sci & Technol, Dept Chem, Chennai 603203, Tamil Nadu, India
关键词
FACILE SYNTHESIS; HIGH-ENERGY; ARRAYS; NANOSHEETS; OXIDES; NANOPARTICLES; CAPACITANCE; NANOFLAKES; GRAPHENE;
D O I
10.1007/s10854-019-00821-3
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Transition metal oxides with metallic composites have greater attention for hybrid supercapacitor due to their excellent electrochemical performance and low cost. In this study, the preparation of manganese dioxide/nickel oxide (MnO2/NiO) nanocomposite via a facile hydrothermal method is reported. The crystallographic and morphological features were studied by Powder XRD, FTIR, HRSEM, EDX and TEM analysis. Cyclic voltammetry, galvanostatic charge-discharge and impedance analysis are implemented in order to examine the applicability of the MnO2/NiO nanocomposite electrode material as a supercapacitor. The MnO2/NiO composites revealed good electrochemical performance by exhibiting a specific capacitance of 247Fg(-1) at the discharge current density rate of 0.5Ag(-1) using 1M KOH as the electrolyte. Moreover, the composite electrode shows enhanced cycling stability. The improvement in specific capacitance of the MnO2/NiO composite is primarily due to its hybrid structure, which offers a better contact of surface of electrode and electrolyte, and active sites with large scale. These results expose the development of MnO2/NiO electrode material shown enhanced performance for supercapacitors.
引用
收藏
页码:5222 / 5232
页数:11
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