Transition metal-catalyzed iodine(III)-mediated nitrene transfer reactions: efficient tools for challenging syntheses

被引：158

作者：

Darses, B. ^{[1
]}

Rodrigues, R. ^{[1
]}

Neuville, L. ^{[1
]}

Mazurais, M. ^{[1
]}

Dauban, P. ^{[1
]}

机构：

[1] Univ Paris Saclay, Univ Paris Sud, CNRS UPR 2301, Inst Chim Subst Nat, 1 Av Terrasse, F-91198 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 03期

关键词：

C-H AMINATION; IMINOIODANE-MEDIATED AZIRIDINATION; CALCIUM SENSING RECEPTOR; STEREOSELECTIVE-SYNTHESIS; INTERMOLECULAR AMINATION; ALKENE AZIRIDINATION; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; INTRAMOLECULAR AMIDATION; C(SP(3))-H AMINATION;

D O I：

10.1039/c6cc07925c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The significant progress made in the area of transition metal-catalyzed nitrene transfer into C-H or C = C bonds mediated by iodine(III) oxidants has been translated into many elegant synthetic applications. This feature article summarizes the main total syntheses that take advantage of such reactions, thereby highlighting that catalytic C(sp(3))-H amination and alkene aziridination reactions have carved out their place in the organic chemist's toolbox.

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页码：493 / 508

页数：16

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