Low Resistivity Tin-Doped Copper Nanowires

被引:0
作者
Lin, Ching-Yen [1 ]
Wang, Chiu-Yen [1 ]
Hung, Min-Hsiu [1 ]
Liu, Tzu-Ling [1 ]
Yew, Tri-Rung [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan
关键词
Cu(Sn); chemical vapor deposition; electrical resistivity; interconnect; nanowire; Su-doped Cu nanowires; ELECTROMIGRATION; CU; GROWTH; WLR;
D O I
10.1109/LED.2013.2246133
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
This letter presents Sn-doped Cu nanowires, Cu(Sn) NWs, synthesized by chemical vapor deposition using Cu and SnCl2 powders as precursors at low temperature (<= 400 degrees C) and their electrical properties. The Sn not only plays a role as a catalyst to enhance reduction of Cu, but also as a dopant for Cu(Sn) NWs. The Sn thickness, substrate pretreatment, substrate temperature, process pressure, and precursor compositions are optimized to obtain high-density nanowires. Results show that Cu(Sn) NWs, 30 mu m in length and 50-620 nm in diameter, are synthesized successfully at 350 degrees C. The Cu(Sn) NWs exhibit low resistivity (2.84 mu Omega-cm), which is the lowest value reported thus far, and a failure current density of 3.16 x 10(7) A/cm(2).
引用
收藏
页码:529 / 531
页数:3
相关论文
共 23 条
  • [1] Semiconductor nanowires: optics and optoelectronics
    Agarwal, R.
    Lieber, C. M.
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2006, 85 (03): : 209 - 215
  • [2] Annealing behavior of Cu and dilute Cu-alloy films: Precipitation, grain growth, and resistivity
    Barmak, K
    Gungor, A
    Cabral, C
    Harper, JME
    [J]. JOURNAL OF APPLIED PHYSICS, 2003, 94 (03) : 1605 - 1616
  • [3] Large-scale synthesis of high-quality ultralong copper nanowires
    Chang, Y
    Lye, ML
    Zeng, HC
    [J]. LANGMUIR, 2005, 21 (09) : 3746 - 3748
  • [4] Extraordinary mobility in semiconducting carbon nanotubes
    Durkop, T
    Getty, SA
    Cobas, E
    Fuhrer, MS
    [J]. NANO LETTERS, 2004, 4 (01) : 35 - 39
  • [5] Direct observation of electromigration and induced stress in Cu nanowire
    Fujisawa, S
    Kikkawa, T
    Kizuka, T
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 2003, 42 (12A): : L1433 - L1435
  • [6] Carbon nanotube growth technologies using tantalum barrier layer for future ULSIs with Cu/low-k interconnect processes
    Horibe, M
    Nihei, M
    Kondo, D
    Kawabata, A
    Awano, Y
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (7A): : 5309 - 5312
  • [7] Kawabata A, 2008, IEEE INT INTERC TECH, P237
  • [8] Copper nanowires with a five-twinned structure grown by chemical vapor deposition
    Kim, Changwook
    Gu, Wenhua
    Briceno, Martha
    Robertson, Ian M.
    Choi, Hyungsoo
    Kim, Kyekyoon
    [J]. ADVANCED MATERIALS, 2008, 20 (10) : 1859 - +
  • [9] LAMPEONNERUD C, 1991, J PHYS IV, V1, P881
  • [10] IN-SITU SCANNING ELECTRON-MICROSCOPE COMPARISON STUDIES ON ELECTROMIGRATION OF CU AND CU(SN) ALLOYS FOR ADVANCED CHIP INTERCONNECTS
    LEE, KL
    HU, CK
    TU, KN
    [J]. JOURNAL OF APPLIED PHYSICS, 1995, 78 (07) : 4428 - 4437