A novel hydrogen-bonded three-dimensional network complex containing nickel

被引：0

作者：

Wang, L ^{[1
]}

Juan, L ^{[1
]}

Wang, EB ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2004年 / 20卷 / 02期

关键词：

pi-pi stacking; hydrogen-bonding interaction; three-dimensional (3D) network; 2,6-pyridinedicarboxylic acid;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel complex, (H(3)O)(2)[Ni(2,6-pydc)(2)] . 2H(2)O was synthesized in an aqueous solution and characterized by means of single-crystal X-ray diffraction, elemental analyses and IR spectra. The X-ray structural analysis revealed that the novel compound forms three-dimensional (3D) networks by both pi-pi stacking and hydrogen-bonding interactions. The crystal data for the complex are a = 13.853 (3) nm, b = 9.6892 (19) nm, c = 13.732 (3) nm, alpha = 90.00degrees, beta = 115.52 (3)degrees, gamma = 90.00degrees, Z = 3, R(1) = 0.0786, wR(2) = 0.1522.

引用

页码：127 / 130

页数：4

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