Characterization of a humic gel synthesized from an activated epoxy silica gel

被引:3
作者
Barbot, C
Czerwinski, K
Buckau, G
Kim, JI
Moulin, V
Vial, M
Pieri, J
Durand, JP
Goudard, F
机构
[1] Univ Nantes, GERMETRAD, Lab Biochim & Radiobiochim, F-44322 Nantes, France
[2] MIT, Dept Nucl Engn, Cambridge, MA 02139 USA
[3] Forschungszentrum Karlsruhe, Inst Nukl Entsorgung, D-76021 Karlsruhe, Germany
[4] CEA, CE Saclay, Div Nucl Energy, DEN,DDIN, F-91191 Gif Sur Yvette, France
关键词
humic acid; epoxy silica; humic gel; DRIFTS; potentiometric titrations;
D O I
10.1524/ract.2002.90.4_2002.211
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Purified humic acid has been covalently bound on activated epoxy silica gel particles. Determination of physical properties and chemical properties was conducted in order to characterize the material at different stages of the preparation. FTIR spectra and the PEC of the surface bound humic acid is very similar to that of humic acid starting material. This shows that the humic acid was not deteriorated during the surface binding process. This humic gel can be used as an analogue for sediment associated humic acid, with the advantage that covalently bound humic acid does not desorb, and thus allows for simple species separation between non-complexed and humic bound metal ions in batch and column experiments.
引用
收藏
页码:211 / 218
页数:8
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