Synthesis and Magnetic Property of a Novel Tetracyanonickelate(II) Complex with Discrete Water Cluster (H2O)4

被引：2
作者：
Cui Hong-Xia [1 ]
机构：
[1] Shengli Coll China Univ Petr, Dept Chem & Chem Engn, Dongying 257097, Shandong, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 07期
关键词：
tetracyanonickelate; crystal structure; water cluster; magnetic property; PRUSSIAN BLUE; CRYSTAL-STRUCTURE; AB-INITIO; NICKEL(II); CHEMISTRY; EXCHANGE; DESIGN; N=1-6; NI; CU;
D O I：
10.3969/j.issn.1001-4861.2013.00.217
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A tetracyanonickelate-nickel complex {[Ni(i-Pr(3)TACN)][Ni(CN)(4)](2)center dot H2O (1) has been synthesized by self-assembly using K-2[Ni(CN)(4)] and [NiPr(3)TACN]Cl-2, (i-Pr(3)TACN=1,4, 7-Triisopropyl-1,4,7-Triazacyclononane). The X-ray character shows there is a discrete tetramer water clusters in 1. Within the cluster, the four water molecules are fully coplanar and each water monomer acts as both single hydrogen bond donor and acceptor. The magnetic susceptibility shows an antiferromagnetic interaction between the Ni(II) ions and the J values is -1.09 cm(-1). CCDC: 727702.
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页码：1485 / 1489
页数：5
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