Fluoroalkyl sulfides as photoredox-active coupling reagents for alkene difunctionalization

被引：42

作者：

Kosobokov, Mikhail D. ^{[1
]}

Zubkov, Mikhail O. ^{[1
]}

Levin, Vitalij V. ^{[1
]}

Kokorekin, Vladimir A. ^{[1
]}

Dilman, Alexander D. ^{[1
]}

机构：

[1] ND Zelinskii Inst Organ Chem, Leninsky Prosp 47, Moscow 119991, Russia

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 66期

基金：

俄罗斯科学基金会;

关键词：

TRANSFER RADICAL-ADDITION; LIGHT; CYANOFLUOROALKYLATION; CYCLIZATION; FLUORINE; OLEFINS; SYSTEMS; ATRA;

D O I：

10.1039/d0cc04617e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A visible-light-promoted fluoroalkylation-thiolation of alkenes is described. A 4-tetrafluoropyridinylthio fragment serves as a photoredox-active group in the initiation step and undergoes a radical group transfer, which is important for the reaction efficiency. In the primary products, the pyridinylthio substituent may be further functionalizedviaradical processes or an aromatic substitution reaction.

引用

页码：9453 / 9456

页数：4

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