Comprehensive Study of the Growth Mechanism and Photoelectrochemical Activity of a BiVO4/Bi2S3 Nanowire Composite

被引：38
作者：
Hong, Changhyun [1 ,2 ]
Kim, Yong-Il [3 ]
Seo, Jong Hyeok [1 ,2 ]
Kim, Ji Hyeon [1 ,2 ]
Ma, Ahyeon [1 ,2 ]
Lim, Yun Ji [1 ,2 ]
Seo, Dongho [1 ,2 ]
Baek, So Yeon [1 ,2 ]
Jung, Haeun [1 ,2 ]
Nam, Ki Min [1 ,2 ]
机构：
[1] Pusan Natl Univ, Dept Chem, Busan 46241, South Korea
[2] Pusan Natl Univ, Chem Inst Funct Mat, Busan 46241, South Korea
[3] Korea Res Inst Stand & Sci KRISS, Daejeon 34113, South Korea
来源：
ACS APPLIED MATERIALS & INTERFACES | 2020年 / 12卷 / 35期
基金：
新加坡国家研究基金会;
关键词：
BiVO4; Bi2S3; nanowire; BiVO4/Bi2S3; composite; growth mechanism; photoelectrochemistry; BI2S3; NANOWIRE; QUANTUM DOTS; SOLAR; BI2MOO6; CR(VI); ARRAY; WATER;
D O I：
10.1021/acsami.0c07577
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A BiVO4/Bi2S3 composite comprising Bi2S3 nanowires on top of a BiVO4 film was prepared via hydrothermal reaction. Because additional Bi3+ ions were not delivered during the reaction, BiVO4 served as the Bi3+ ion source for the development of Bi2S3. A detailed growth mechanism of the nanowire was elucidated by an analysis of the concentration gradient of Bi3+ and S2- ions during the reaction. The in situ growth was followed by the etching of BiVO4 to Bi3+ and VO43- ions and regrowth to Bi2S3, which resulted in the rapid evolution of nanowires on the BiVO4 substrate. The fabricated BiVO4/Bi2S3NW composite exhibited an improved photoelectrochemical activity compared to other Bi2S3 samples. The improved efficiency was mainly attributed to both improved charge separation and effective adhesion obtained by the in situ growth.
引用
收藏
页码：39713 / 39719
页数：7
相关论文
共 38 条
  • [1] PHOTOELECTROCHEMISTRY
    BARD, AJ
    [J]. SCIENCE, 1980, 207 (4427) : 139 - 144
  • [2] Direct Growth of BiVO4/Bi2S3 Nanorod Array on Conductive Glass as Photocatalyst for Enhancing the Photoelectrochemical Performance
    Chen, Hong-Qin
    Lin, Lu-Yin
    Chen, Shan-Lung
    [J]. ACS APPLIED ENERGY MATERIALS, 2018, 1 (11): : 6089 - 6100
  • [3] Environmentally benign synthesis of branched Bi2O3-Bi2S3 photocatalysts by an etching and re-growth method
    Chen, Lang
    He, Jie
    Yuan, Qing
    Liu, Ying
    Au, Chak-Tong
    Yin, Shuang-Feng
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (03) : 1096 - 1102
  • [4] Understanding Reaction Kinetics by Tailoring Metal Co-catalysts of the BiVO4 Photocatalyst
    Choe, Hye Rin
    Kim, Ji Hyeon
    Ma, Ahyeon
    Jung, Haeun
    Kim, Ha Young
    Nam, Ki Min
    [J]. ACS OMEGA, 2019, 4 (15): : 16597 - 16602
  • [5] Metal-semiconductor double shell hollow nanocubes for highly stable hydrogen generation photocatalysts
    Choi, Woong
    Park, Garam
    Bae, Kyung-Lyul
    Choi, Ji Yong
    Nam, Ki Min
    Song, Hyunjoon
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (35) : 13414 - 13418
  • [6] TOPAS and TOPAS-Academic: an optimization program integrating computer algebra and crystallographic objects written in C plus
    Coelho, Alan A.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2018, 51 : 210 - 218
  • [7] Long-lived charge separated states in nanostructured semiconductor photoelectrodes for the production of solar fuels
    Cowan, Alexander J.
    Durrant, James R.
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (06) : 2281 - 2293
  • [8] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
    FUJISHIMA, A
    HONDA, K
    [J]. NATURE, 1972, 238 (5358) : 37 - +
  • [9] Realization of Efficient Field Emitter Based on Reduced Graphene Oxide-Bi2S3 Heterostructures
    Gote, Gorkshnath H.
    Bhopale, Somnath R.
    More, Mahendra A.
    Late, Dattatray J.
    [J]. PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2019, 216 (18):
  • [10] The interlace of Bi2S3 nanowires with TiO2 nanorods: An effective strategy for high photoelectrochemical performance
    Han, Minmin
    Jia, Junhong
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 481 : 91 - 99
1234