Water activated by atomic oxygen on Au(111) to oxidize CO at low temperatures

被引：106
作者：
Kim, Tae S.
Gong, Jinlong
Ojifinni, Rotimi A.
White, J. M.
Mullins, C. Buddie
机构：
[1] Univ Texas, Dept Chem Engn & Chem, Ctr Nano & Mol Sci & Technol, Austin, TX 78712 USA
[2] Texas Mat Inst, Austin, TX 78712 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 19期
关键词：
D O I：
10.1021/ja058263m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Au(111) surface was populated with atomic oxygen [16O] followed by oxygen-labeled water [H218O] at surface temperatures as low as 77 K. When a CO beam was impinged on this surface, both [C16O16O] and [C16O18O] were produced. The results strongly suggest the direct involvement and promoting role of water in CO oxidation on oxygen covered Au(111) at low temperatures. Copyright © 2006 American Chemical Society.
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页码：6282 / 6283
页数：2
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