The Effects of Slag Compositions on the Coal Gasification Reaction in Molten Blast Furnace Slag

被引：16
作者：
Li, P. [1 ]
Yu, Q. [1 ]
Qin, Q. [1 ]
Du, W. [1 ]
机构：
[1] Northeastern Univ, Sch Met & Mat, Shenyang 110819, Liaoning, Peoples R China
来源：
ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS | 2014年 / 36卷 / 01期
关键词：
blast furnace; coal gasification; economic and environmental evaluation; high temperature; molten slag; waste heat recovery; RECOVERY; HEAT; FEASIBILITY; SURFACE;
D O I：
10.1080/15567036.2011.606870
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The char-CO2 gasification reactions in molten blast furnace slag were studied kinetically by the isothermal thermogravimetry using STA409PC thermal analyzer. The effects of slag compositions (SiO2, MgO, CaO, and Al2O3) on gasification reaction were investigated. The results showed that CaO has certain catalytic effects on gasification reaction; however, when the gasification reaction temperature reached a certain value, the catalytic effect of CaO on gasification could be neglected. MgO also played a catalytic role in the gasification reaction. In this experiment, the gasification reaction rate increased with increasing the MgO content from 8 to 10 mass%, whereas it decreased with increasing the MgO content from 10 to 12 mass%. SiO2 had no catalytic effect on gasification reaction.
引用
收藏
页码：73 / 79
页数：7
相关论文
共 10 条
[1]   Thermodynamic analysis of thermochemical recovery of high temperature wastes [J].
Akiyama, T ;
Oikawa, K ;
Shimada, T ;
Kasai, E ;
Yagi, J .
ISIJ INTERNATIONAL, 2000, 40 (03) :286-291
[2]   A study on dissolution kinetics of carbon in liquid iron bath [J].
Bandyopadhyay, D ;
Singh, SD ;
Sanyal, D ;
Singh, KK ;
Singh, KN .
CHEMICAL ENGINEERING JOURNAL, 2003, 94 (02) :79-92
[3]   Rate of methane-steam reforming reaction on the surface of molten BF slag - for heat recovery from molten slag by using a chemical reaction [J].
Kasai, E ;
Kitajima, T ;
Akiyama, T ;
Yagi, J ;
Saito, F .
ISIJ INTERNATIONAL, 1997, 37 (10) :1031-1036
[4]   Feasibility Study for the System of Coal Gasification by Molten Blast Furnace Slag [J].
Li, Peng ;
Qin, Qin ;
Yu, Qingbo ;
Du, Wenya .
MANUFACTURING SCIENCE AND ENGINEERING, PTS 1-5, 2010, 97-101 :2347-2351
[5]   Feasibility study for recovering waste heat in the steelmaking industry using a chemical recuperator [J].
Maruoka, N ;
Mizuochi, T ;
Purwanto, H ;
Akiyama, T .
ISIJ INTERNATIONAL, 2004, 44 (02) :257-262
[6]   Exergy recovery from steelmaking off-gas by latent heat storage for methanol production [J].
Maruoka, Nobuhiro ;
Akiyama, Tomohiro .
ENERGY, 2006, 31 (10-11) :1632-1642
[7]  
PURMANTO H, 2006, INT J HYDROGEN ENERG, V31, P491
[8]  
PURWANTO H, 2005, CURR ADV MAT PROCESS, V18, P241
[9]   Effects of slag compositions on the rate of methane-steam reaction [J].
Shimada, T ;
Kochura, V ;
Akiyama, T ;
Kasai, E ;
Yagi, J .
ISIJ INTERNATIONAL, 2001, 41 (02) :111-115
[10]   A model of char capture by molten slag surface under high-temperature gasification conditions [J].
Shimizu, T ;
Tominaga, H .
FUEL, 2006, 85 (02) :170-178
1