Hyperbranched Polymer Assisted Curing and Repairing of an Epoxy Coating

被引：62

作者：

Han, Jiarui ^{[1
,3
]}

Liu, Tuan ^{[2
]}

Zhang, Shuai ^{[2
]}

Hao, Cheng ^{[2
]}

Xin, Junna ^{[2
]}

Guo, Baohua ^{[1
]}

Zhang, Jinwen ^{[2
]}

机构：

[1] Tsinghua Univ, Dept Chem Engn, Key Lab Adv Mat, Minist Educ, Beijing 100084, Peoples R China

[2] Washington State Univ, Sch Mech & Mat Engn, Composite Mat & Engn Ctr, Pullman, WA 99164 USA

[3] Washington State Univ, Pullman, WA 99164 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2019年 / 58卷 / 16期

基金：

中国国家自然科学基金;

关键词：

SHAPE-MEMORY; STRESS-RELAXATION; GLASS-TRANSITION; VITRIMERS; NETWORKS; PLASTICITY;

D O I：

10.1021/acs.iecr.9b00800

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Imparting repairability to a thermoset coating without compromising other properties is desirable. In this work, a catalyst-free and repairable epoxy coating based on vitrimer chemistry was developed by using a mixture of bisphenol A epoxy (DER) and a hyperbranched epoxy (HBE) as matrix, and succinic anhydride (SA) as curing agent. The abundant hydroxyl groups in the HBE accelerate both the rates of curing and the dynamic transesterification. The presence of DER epoxy ensures the low viscosity of the coating, and its high epoxy value results in the formation of sufficient ester bonds after curing. When the epoxy curing system is used as coating for tin plate, the coating shows excellent hardness and adhesion properties. The scratch on the surface can be repaired at 150 degrees C without external pressure. The repaired coating well protects the metal substrate from corrosion in NaCl aqueous solution.

引用

页码：6466 / 6475

页数：10

共 50 条

[41] Reprocessable Acid-Degradable Polycarbonate Vitrimers [J].

Snyder, Rachel L. ;

Fortman, David J. ;

De Hoe, Guilhem X. ;

Hillmyer, Marc A. ;

Dichtel, William R. .

MACROMOLECULES, 2018, 51 (02) :389-397

[42] Recyclable cross-linked hydroxythioether particles with tunable structures via robust and efficient thiol-epoxy dispersion polymerizations [J].

Tan, Jiaojun ;

Li, Chunmei ;

De Bruycker, Kevin ;

Zhang, Guoxian ;

Gu, Junwei ;

Zhang, Qiuyu .

RSC ADVANCES, 2017, 7 (82) :51763-51772

[43] Self-healing gels based on constitutional dynamic chemistry and their potential applications [J].

Wei, Zhao ;

Yang, Jian Hai ;

Zhou, Jinxiong ;

Xu, Feng ;

Zrinyi, Miklos ;

Dussault, Patrick H. ;

Osada, Yoshihito ;

Chen, Yong Mei .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (23) :8114-8131

[44] Dual-Triggered and Thermally Reconfigurable Shape Memory Graphene-Vitrimer Composites [J].

Yang, Zenghui ;

Wang, Qihua ;

Wang, Tingmei .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (33) :21691-21699

[45] Influence of stoichiometry on the glass transition and bond exchange reactions in epoxy thermoset polymers [J].

Yu, Kai ;

Taynton, Philip ;

Zhang, Wei ;

Dunn, Martin L. ;

Qi, H. Jerry .

RSC ADVANCES, 2014, 4 (89) :48682-48690

[46] Improving hydrophilicity and protein resistance of poly(vinylidene fluoride) membranes by blending with amphiphilic hyperbranched-star polymer [J].

Zhao, Yong-Hong ;

Zhu, Bao-Ku ;

Kong, Li ;

Xu, You-Yi .

LANGMUIR, 2007, 23 (10) :5779-5786

[47] Thermoset Shape-Memory Polyurethane with Intrinsic Plasticity Enabled by Transcarbamoylation [J].

Zheng, Ning ;

Fang, Zizheng ;

Zou, Weike ;

Zhao, Qian ;

Xie, Tao .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (38) :11421-11425

[48] Poly(butylene terephthalate)/Glycerol-based Vitrimers via Solid-State Polymerization [J].

Zhou, Yanwu ;

Goossens, Johannes G. P. ;

Sijbesma, Rint P. ;

Heuts, Johan P. A. .

MACROMOLECULES, 2017, 50 (17) :6742-6751

[49]

2016, J MATER CHEM C, V4, P6220, DOI DOI 10.1039/C6TC02383E

[50]

2018, GREEN CHEM, V20, P2995, DOI DOI 10.1039/C8GC01299G

← 1 2 3 4 5 →