Novel Effective Catalyst Systems Based on Titanium(IV) Alkoxide Complexes for Copolymerization of Ethylene and Hexene-1

被引：5

作者：

Tuskaev, V. A. ^{[1
,2
]}

Gagieva, S. Ch. ^{[1
]}

Lyadov, A. S. ^{[3
]}

Kurmaev, D. A. ^{[1
]}

Nikiforova, G. G. ^{[2
]}

Vasil'ev, V. G. ^{[2
]}

Zubkevich, S. V. ^{[1
]}

Saracheno, D. ^{[5
]}

Sizov, A. I. ^{[1
]}

Privalov, V. I. ^{[4
]}

Bulychev, B. M. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[3] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia

[4] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[5] Russian Acad Sci, Higher Chem Coll, Moscow 119991, Russia

来源：

PETROLEUM CHEMISTRY | 2020年 / 60卷 / 07期

基金：

俄罗斯科学基金会; 俄罗斯基础研究基金会;

关键词：

titanium compounds; OO-type ligands; ethylene; hexene-1; copolymerization; LIGANDS;

D O I：

10.1134/S0965544120070142

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The catalytic activity of bis(isopropoxo)titanium(4+) complexes containing 1,2-diolate ligands activated with aluminum alkyl chlorides and dibutyl magnesium in the copolymerization of ethylene and hexene-1 has been studied. The effect of the precatalyst structure and the organoaluminum activator composition on the catalytic activity, the incorporation of hexene-1, and the copolymer microstructure has been studied. The synthesized copolymers have been characterized by DSC, GPC, and(13)C NMR. The complexes containing perfluorophenyl substituents exhibit the highest activity in this set and provide the highest degree of incorporation of the comonomer. The replacement of Et2AlCl with Et(3)Al(2)Cl(2)leads to a significant decrease in both productivity and the degree of incorporation of hexene-1 into the copolymer. The mechanical properties of the resulting copolymers have been studied.

引用

页码：827 / 833

页数：7

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