Palladium-catalyzed synthesis of 3-(alkylamino)isoindolin-1-ones by carbonylative cyclization of 2-bromobenzaldehyde with primary amines

被引：35

作者：

Cho, CS

Jiang, LH

Lee, DY

Shim, SC

Lee, HS

Cho, SD

机构：

[1] CATHOLIC UNIV,DEPT CHEM,KYONGSAN 712702,SOUTH KOREA

[2] CHOSUN UNIV,DEPT CHEM,KWANGJU 501759,SOUTH KOREA

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1997年 / 34卷 / 04期

关键词：

D O I：

10.1002/jhet.5570340446

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Bromobenzaldehyde reacts with an excess of primary amines under a carbon monoxide in the presence of a catalytic amount of bis(triphenylphosphine)palladium(II) chloride together with triethylamine to give the corresponding 3-(alkylamino)isoindolin-1-ones in good yields.

引用

收藏

页码：1371 / 1374

页数：4

相关论文

共 20 条

[1] SUNLAMP-IRRADIATED PHASE-TRANSFER CATALYSIS .1. COBALT CARBONYL CATALYZED SRN1 CARBONYLATIONS OF ARYL AND VINYL HALIDES [J].

BRUNET, JJ ;

SIDOT, C ;

CAUBERE, P .

JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (08) :1166-1171

[2] Synthesis of isoindolinones via carbonylative cyclisation of 2-(2-bromophenyl)-2-oxazolines by a bimetallic palladium-nickel catalyst system [J].

Cho, CS ;

Lee, JW ;

Lee, DY ;

Shim, SC ;

Kim, TJ .

CHEMICAL COMMUNICATIONS, 1996, (18) :2115-2116

[3]

Cho CS, 1996, B KOR CHEM SOC, V17, P1095

[4]

Colquhoun H.M., 1991, Carbonylation, Direct Synthesis of Carbonyl Compounds

[5] ACYLPALLADATION OF INTERNAL ALKYNES AND PALLADIUM-CATALYZED CARBONYLATION OF (Z)-BETA-IODOENONES AND RELATED DERIVATIVES PRODUCING GAMMA-LACTONES AND GAMMA-LACTAMS [J].

COPERET, C ;

SUGIHARA, T ;

WU, GZ ;

SHIMOYAMA, I ;

NEGISHI, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (12) :3422-3431

[6]

GURAM AS, 1995, ANGEW CHEM INT EDIT, V34, P1348, DOI 10.1002/anie.199513481

[7] HOMOGENEOUS CATALYSIS IN REACTIONS OF OLEFINICSUBSTANCES .V. HYDROGENATION OF SOYBEAN OIL METHYL ESTER WITH TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE PALLADIUM CATALYSTS [J].

ITATANI, H ;

BAILAR, JC .

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1967, 44 (02) :147-&

[8] CYCLOCARBONYLATION CATALYZED BY PALLADIUM COMPLEXES [J].

IWASAKI, M ;

ISHII, Y ;

HIDAI, M .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1991, 49 (10) :909-918

[9] A new indirect application of aggregative activation: Synthesis of esters by cobalt-catalyzed carbonylation of aryl, heterocyclic, and vinyl halides under atmospheric pressure [J].

Marchal, J ;

Bodiguel, J ;

Fort, Y ;

Caubere, P .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (26) :8336-8340

[10] REACTIONS AND SYNTHESES WITH ORGANOMETALLIC COMPOUNDS .7. SYNTHESIS OF BENZOLACTAMS BY PALLADIUM-CATALYZED AMIDATION [J].

MORI, M ;

CHIBA, K ;

BAN, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (09) :1684-1687